Radiation-sensitive mixture and use thereof
AssigneeBASF SE
InventorsRainer Blum, Gerd Rehmer, Hans Schupp
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Abstract
Radiation-reactive mixtures suitable for producing insulating layers and printed circuits are composed of certain precursors for preparing polyimides polyisoindoloquinazolinediones, polyoxazinediones, polyquinazolinediones or polyquinazolones and aryl-containing carbonyl compounds which when excited by UV radiation are capable of hydrogen abstraction, these mixtures undergoing solubility differentiation on irradiation with actinic light.
Claims21
A radiation-sensitive mixture which is suitable for preparing a polyamide, a polyisoindoloquinazolinedione, a polyoxazinedione, a polyquinazolinedione or a polyquinazolone and which on irradiation with actinic light undergoes solubility differentiation, which mixture comprises
- (a) one or more precursors having structural elements of the general formula (I) ##STR14## where A is --O--, --NH-- or a single bond,
- Q is an unsubstituted or halogen-substituted aromatic tetravalent radical, wherein two at a time of the valences are adjacent to each other,
- B.sup.1 is --O-- or --NR.sup.4 --,
- B.sup.2 is --NH--CO--NH--, --NH--CO--O--, --NH--CO-- or a single bond,
- R.sup.1 is H, alkyl, aryl, an ethylenically unsaturated radical or a readily hydrogen-donating radical selected from the group consisting of isoalkyls, aminoisoalkyls, and groups of the following general formulae:
- ##STR15## where n is 2 or 3,
- R.sup.2 is a bivalent aliphatic or aromatic radical or a single bond,
- R.sup.3 is a bivalent aliphatic, cycloaliphatic, aromatic radical which may be halogen-substituted,
- R.sup.4 is H or straight-chain or branched alkyl which may be halogen-substituted, and
- R.sup.5 is alkyl, aryl, halogen-substituted alkyl or halogen-substituted aryl,
- with the proviso that at least one of Q and R.sup.3 has a readily abstractable hydrogen atom,
- (b) one or more aryl-containing carbonyl compounds which when excited by UV radiation are capable of hydrogen abstraction, and optionally
- (c) one or more substances selected from the group consisting of a photoinitiator, a photosensitizer, a (leuco)dye and an aliphatic ketone.
Dependencies are inferred from the claim text.