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US 5,268,114 AGranted
N-alkenyl substituted amine-N-oxide stabilizers
AssigneeCiba-Geigy Corporation
InventorsPaul Odorisio, Joseph E. Babiarz
Life of this patent
Estimating the term…
Abstract
N-Alkenyl substituted hydroxylamines of formula I ##STR1## where R.sub.1 and R.sub.2 are independently hydrogen, alkyl, aryl or phenylalkyl, and R.sub.3 to R.sub.7 are independently hydrogen, alkyl or substituted alkyl are very effective process stabilizers for polymeric systems providing melt flow stabilization and resistance to discoloration during processing at elevated temperatures as well as effective stabilizers for lubricant compositions.
Claims6
A stabilized composition which comprises
- (a) a lubricant subject to oxidative, thermal or actinic-induced degradation, and
- (b) an effective stabilizing amount of a compound of formula I ##STR6## wherein R.sub.1 and R.sub.2 are independently hydrogen, a straight or branched chain alkyl of 1 to 36 carbon atoms, alkyl of 1 to 18 carbon atoms terminated by a group --OR.sub.8, --NR.sub.9 R.sub.10, --SR.sub.11, --COOR.sub.12 or --CONR.sub.13 R.sub.14 or interrupted by arylene of 6 to 10 carbon atoms, --O--, --S--, --SO--, --SO.sub.2 --, --COO--, --OCO--, --CONR.sub.15 --, --NR.sub.15 CO-- or --NR.sub.16 -- where R.sub.8, R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13, R.sub.14, R.sub.15 and R.sub.16 are independently hydrogen, alkyl of 1 to 18 carbon atoms or alkenyl of 3 to 6 carbon atoms;
- or R.sub.1 and R.sub.2 are independently cycloalkyl of 5 to 12 carbon atoms, phenylalkyl of 7 to 15 carbon atoms, said phenylalkyl substituted on the phenyl ring by alkyl of 1 to 18 carbon atoms or by .alpha.-cumyl;
- aryl of 6 to 14 carbon atoms or said aryl substituted by one or two alkyl of 1 to 24 carbon atoms,
- R.sub.3 and R.sub.4 are independently hydrogen, alkyl of 1 to 9 carbon atoms, said alkyl substituted by --OH or by acetoxy;
- alkenyl of 3 to 6 carbon atoms or aryl of 6 to 10 carbon atoms, and
- R.sub.5, R.sub.6 and R.sub.7 are independently hydrogen, alkyl of 1 to 9 carbon atoms, said alkyl substituted by --OH or by acetoxy;
- alkenyl of 3 to 6 carbon atoms, aryl of 6 to 10 carbon atoms, or a group of formula II ##STR7## or R.sub.3 and R.sub.4, or R.sub.3 and R.sub.5, or R.sub.3 and R.sub.7, or R.sub.4 and R.sub.5, or R.sub.4 and R.sub.7, or R.sub.5 and R.sub.6, or R.sub.6 and R.sub.7 together are a straight or branched chain alkylene of 2 to 8 carbon atoms to form a cycloalkyl or cycloalkenyl ring with 5 or 6 ring atoms.
5 more elements
Dependencies are inferred from the claim text.