1-aminoanthraquinone dye compound having fiber reactive group through sulfur or oxygen atom at 4-position and imparting red color

A compound represented by the following formula (I):

• ##STR610## wherein R is hydrogen, alkyl, cyclohexyl, phenyl, alkylcarbonyl, benzoyl, alkylsulfonyl or phenylsulfonyl, said alkyl, alkylcarbonyl and alkylsulfonyl each being unsubstituted or substituted by methoxy, ethoxy, chloro, bromo, acetylamino, propionylamino, nitro, cyano, carbamoyl, carboxy, hydroxy, sulfato or sulfo, and said cyclohexyl, phenyl, benzoyl and phenylsulfonyl each being unsubstituted or substituted by methyl, ethyl, methoxy, ethoxy, chloro, bromo, acetylamino, propionylamino, nitro, cyano, carbamoyl, carboxy, hydroxy, sulfato or sulfo;
• ep1 R.sub.1 and R.sub.2 independently of one another are each hydrogen, halogen or sulfo;
• l is 1 or 2;
• X is hydrogen, alkyl, halogen, carboxy or sulfo;
• and
• Y is a group of the formula
• --V.sub.1 --A.sub.1 --U
• in which V.sub.1 is a divalent group of --O-- or --S--;
• U is a group of the following formula (3) or (4), the formula (3) being ##STR611## wherein W.sub.1 is a divalent group of --NR.sub.5 -- in which R.sub.5 is hydrogen or alkyl unsubstituted or substituted by hydroxy, cyano, C.sub.1 -C.sub.4 alkoxy, chloro, bromo, carboxy, carbamoyl, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylcarbonyloxy, sulfo or sulfamoyl, Z.sub.1 is a fiber reactive group, and l.sub.1 is 0 or 1, and the formula (4) being ##STR612## wherein R.sub.7 is hydrogen or alkyl, R.sub.8 is hydrogen or alkyl unsubstituted or substituted by hydroxy, B is phenylene unsubstituted or substituted by methyl, ethyl, methoxy, ethoxy, chloro, bromo, sulfo, carboxy or nitro, or napthylene unsubstituted or substituted by sulfo, Q is vinyl or --CH.sub.2 CH.sub.2 L in which L is a group capable of being split by the action of an alkali, and T is fluoro, chloro or a group of the following formula (5), (6), (7) or (8), the formula (5) being ##STR613## wherein R.sub.9 and R.sub.10 independently of one another are each hydrogen, alkyl unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy, sulfo, carboxy, hydroxy, chloro, phenyl or sulfato, phenyl unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, sulfo, carboxy or chloro, naphthyl unsubstituted or substituted by hydroxy, carboxy, sulfo, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, or chloro, or benzyl unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, sulfo or chloro, the formula (6) being ##STR614## wherein R.sub.11 is hydrogen or alkyl unsubstituted or substituted by hydroxy, B.sub.1 is phenylene unsubstituted or substituted by methyl, ethyl, methoxy, ethoxy, chloro, bromo, sulfo, carboxy, or nitro, or naphthylene unsubstituted or substituted by sulfo, and Q.sub.1 is vinyl or --CH.sub.2 CH.sub.2 L, in which L is a group capable of being split by the action of an alkali, the formula (7) being ##STR615## wherein R.sub.12, R.sub.13 and R.sub.14 independently of one another are each alkyl unsubstituted or substituted by hydroxy, methoxy, ethoxy, diethylamino, carboxy or sulfato, and the formula (8) being ##STR616## wherein R.sub.15 is hydrogen, cyano, carbamyol, halogen, hydroxy, vinyl, sulfo, carboxy or alkyl unsubstituted or substituted by hydroxy;
• and
• A.sub.1 is a group of the following formula (9), (10), (11) or (12), the formula (9) being ##STR617## wherein R.sub.16, R.sub.17 and R.sub.18 independently of one another are each hydrogen, methyl, ethyl, methoxy, ethoxy, chloro, bromo or carboxy, W.sub.2 is a divalent group of --O--, --S--, --NR.sub.19 -- or --NR.sub.20 CO-- in which R.sub.19 and R.sub.20 independently of one another are each hydrogen or alkyl, m.sub.1 is 0 or 1, m.sub.2 is 0, 1, 2, 3 or 4, and m.sub.3 is 0, 1 or 2, the formula (10) being ##STR618## wherein R.sub.21, R.sub.22, R.sub.23 and R.sub.24 independently of one another are each hydrogen, methyl, ethyl, methoxy, ethoxy, chloro, bromo or carboxy, W.sub.3 is a bridging group of --O--, --S--, --NR.sub.25 -- or --NR.sub.26 CO-- in which R.sub.25 and R.sub.26 independently of one another are each hydrogen or alkyl, n.sub.1 is 0 or 1, and n.sub.2 and n.sub.3 independently of one another are each 0, I or 2, the formula (11) being ##STR619## wherein p is 0, 1, 2 or 3, and the formula (12) being ##STR620## wherein q is an integer of 2 to 6;
• with the proviso that R.sub.1 is hydrogen, R.sub.2 is hydrogen or sulfo and U is the group of the formula (4) as defined hereinabove, when X is sulfo.