Electrophotographic photosensitive member, and electrophotographic apparatus, device unit, and facsimile machine employing the same
AssigneeCanon Kabushiki Kaisha
InventorsTetsuro Kanemaru, Hideyuki Takai, Itaru Yamazaki, Shinya Mayama, Masato Tanaka
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Abstract
The present invention relates to an electrophotographic photosensitive member. The photosensitive member has an electroconductive support and a photosensitive layer formed thereon containing oxytitanium phthalocyanine, and a surface layer of the photosensitive member contains a copolymer having a first and second structural units represented by the formulas ##STR1## Further the invention relates to an electrophotographic apparatus, device unit, and facsimile machine utilizing the electrophotographic photosensitive member.
Claims32
An electrophotographic photosensitive member, comprising an electroconductive support and a photosensitive layer formed thereon, the photosensitive layer containing oxytitanium phthalocyanine, and a surface layer of the photosensitive member containing a copolymer having a first structural unit represented by the structural formula [I]:
- ##STR47## where A is a linear, branched or cyclic alkylidene group, an aryl-substituted alkylidene group, an --CO--, --SO--, or --SO--, the alkylidene group having 1 to 10 carbon atoms;
- R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are each hydrogen, halogen, or an alkyl or alkenyl group having 1 to 4 carbon atoms, and a second structural unit [II]:
- ##STR48## where R5 is an alkylene or alkylidene group having 2 to 6 carbon atoms;
- R.sub.6 and R.sub.7 are each an alkyl group having 1 to 3 carbon atoms, a phenyl group, or a substituted phenyl group;
- n is an integer of from 1 to 200.
An electrophotographic apparatus, comprising an electrophotographic photosensitive member, an image forming means for forming an electrostatic latent image, a developing means for developing the formed latent image, and a transferring means for transferring a developed image to a transfer-receiving material,
- said electrophotographic photosensitive member comprising an electroconductive support and a photosensitive layer formed thereon, the photosensitive layer containing oxytitanium phthalocyanine, and a surface layer of the photosensitive member containing a copolymer having a first structural unit represented by the structural formula [I]:
- ##STR54## where A is a linear, branched or cyclic alkylidene group, an aryl-substituted alkylidene group, an arylene-dialkylidene group, or a group of --O--, --S--, --CO--, --SO--, or --SO.sub.2 --, the alkylidene group having 1 to 10 carbon atoms;
- R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are each hydrogen, halogen or an alkyl or alkenyl group having 1 to 4 carbon atoms, and a second structural unit [II]:
- ##STR55## R.sub.5 is an alkylene or alkylidene group having 2 to 6 carbon atoms;
- R.sub.6 and R.sub.7 are each an alkyl group having 1 to 3 carbon atoms, a phenyl group, or a substituted phenyl group;
- n is an integer of from 1 to 200.
A device unit comprising an electrophotographic photosensitive member, a charging means, a developing means, and a cleaning means,
- said electrophotographic photosensitive member comprising an electroconductive support and a photosensitive layer formed thereon, the photosensitive layer containing oxytitanium phthalocyanine, and a surface layer of the photosensitive member containing a copolymer having a first structural unit represented by the structural formula [I]:
- ##STR56## where A is a linear, branched or cyclic alkylidene group, an aryl-substituted alkylidene group, an arylene-dialkylidene group, or a group of --O--, --S--, --CO--, --SO--, or --SO.sub.2 --, the alkylidene group having 1 to 10 carbon atoms;
- R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are each hydrogen, halogen, or an alkyl or alkenyl group having 1 to 4 carbon atoms, and a second structural unit [II]:
- ##STR57## where R.sub.5 is an alkylene or alkylidene group having 2 to 6 carbon atoms;
- R.sub.6 and R.sub.7 are each an alkyl group having 1 to 3 carbon atoms, a phenyl group, or a substituted phenyl group;
- n is an integer of from 1 to 200, and
- said unit holding integrally the electrophotographic photosensitive member and at least one means selected from a charging means, a developing means, and a cleaning means, and being demountable from the main body of an electrophotographic apparatus.
A facsimile machine comprising an electrophotographic apparatus and an information-receiving means for receiving image information from a remote terminal,
- said electrophotographic apparatus comprising an electrophotographic photosensitive member,
- said electrophotographic photosensitive member comprising an electroconductive support and a photosensitive layer formed thereon, the photosensitive layer containing oxytitanium phthalocyanine, and a surface layer of the photosensitive member containing a copolymer having a first structural unit represented by the structural formula [I]:
- ##STR58## where A is a linear, branched or cyclic alkylidene group, an aryl-substituted alkylidene group, an arylene-dialkylidene group, or a group of --O--, --S--, --CO--, --SO--, or --SO.sub.2 --, the alkylidene group having 1 to 10 carbon atoms;
- R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are each hydrogen, halogen, or an alkyl or alkenyl group having 1 to 4 carbon atoms, and a second structural unit [II]:
- ##STR59## where R.sub.5 is an alkylene or alkylidene group having 2 to 6 carbon atoms;
- R.sub.6 and R.sub.7 are each an alkyl group having 1 to 3 carbon atoms, a phenyl group, or a substituted phenyl group;
- n is an integer of from 1 to 200.
Dependencies are inferred from the claim text.