Production of silica-based MFI zeolites
AssigneeRhone-Poulenc Chimie
InventorsAnne C. Faust, Jean-Louis Guth, Frederique Hoffner, Jean-Michel Popa
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AssigneeRhone-Poulenc Chimie
InventorsAnne C. Faust, Jean-Louis Guth, Frederique Hoffner, Jean-Michel Popa
Estimating the term…
MFI zeolites based on silicon oxide and, optionally, the oxides of titanium, germanium, zirconium and/or tin, are produced by (1) heating an aqueous, homogeneous reaction mixture which comprises (a) an M.sub.2/n SiF.sub.6 complex (I), wherein M is a cation of valency n, optionally, at least one M.sub.2/n T'F.sub.6 complex (II), wherein T' is titanium, zirconium, germanium and/or tin, (b) a reagent providing OH. ions by hydrothermal decomposition and a structuring agent (c), e.g., a tertiary amine or a quaternary ammonium compound, whereby a zeolite precipitate is formed therein, and (2) separating and calcining such precipitate to eliminate structuring agent from the pores and channels of the resulting zeolite.
A process for the production of an MFI zeolite, comprising (1) heating an aqueous, homogeneous reaction medium which comprises (a) an M.sub.2/n SiF.sub.6 complex (I), wherein M is a cation of valency n, a reagent (b) providing OH.sup.- ions by hydrothermal decomposition and a structuring agent (c), whereby a zeolite precipitate is formed therein, and (2) separating and calcining said precipitate to eliminate said structuring agent from the pores and channels of said zeolite.
Dependencies are inferred from the claim text.