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US 5,240,476 AGranted
Process for sulfur removal and recovery from a power generation plant using physical solvent
AssigneeAir Products and Chemicals, Inc.
InventorWilliam P. Hegarty
Life of this patent
Estimating the term…
Abstract
A process for recovery of hydrogen sulfide-free fuel, while maintaining desirable carbon dioxide for combustion in a gas turbine to recover power in an integrated gasification combined cycle power plant and obtaining a rich hydrogen sulfide Claus plant feed gas is described.
Claims7
A process for producing a hydrogen sulfide-free fuel gas for combustion in a gas turbine to produce power using a raw fuel feed gas from an oxygen-enriched gasification, comprising the steps of:
- (a) introducing a raw fuel feed gas from a gasification, which gas is contaminated with hydrogen sulfide and carbon dioxide, into a first separation zone;
- (b) contacting said raw fuel feed gas with a carbon dioxide-loaded liquid solvent selective for said hydrogen sulfide in said first separation zone;
- (c) removing a hydrogen sulfide-free, carbon dioxide-containing fuel gas from said first separation zone, combusting the hydrogen sulfide-free, carbon dioxide-containing fuel gas in a gas turbine and recovering power from the gas turbine;
- (d) removing a hydrogen sulfide-rich, carbon dioxide-containing solvent from said first separation zone and reducing said solvent in pressure;
- (e) heating said reduced pressure solvent to an elevated temperature before separating said reduced pressure solvent into a carbon dioxide-rich stream and a second hydrogen sulfide-rich solvent containing residual carbon dioxide;
- (f) stripping said residual carbon dioxide from said second hydrogen sulfide-rich solvent with nitrogen-rich gas at a pressure below approximately 300 psia to recover a residual carbon dioxide containing nitrogen stripping gas;
- (g) combining said carbon dioxide-rich stream of step (e) and said residual carbon dioxide containing nitrogen stripping gas of step (f) and recycling the resulting combined stream to the hydrogen sulfide-free, carbon dioxide-containing fuel gas;
- (h) stripping the hydrogen sulfide from said second hydrogen sulfide-rich solvent in a regeneration zone using steam to recover a hydrogen sulfide-rich product stream and a hydrogen sulfide-lean solvent;
- and
- (i) combining said hydrogen sulfide-lean solvent with said hydrogen sulfide-free, carbon dioxide-containing fuel gas either outside said first separation zone or in a top tray of said first separation zone, cooling them and separating them into said carbon dioxide-loaded liquid solvent of step (b) and a final hydrogen sulfide-free, carbon dioxide-containing fuel gas for introduction into said gas turbine of step (c).
7 more elements
The process of claim wherein coal is gasified with oxygen-enriched oxidant gas to produce said raw fuel feed gas.
Dependencies are inferred from the claim text.