Recovery of EDTA from steam generator cleaning solutions
AssigneeWestinghouse Electric Corp.
InventorZoltan L. Kardos
Life of this patent
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Abstract
A process for recovering the chelating or complexing agents, particularly ethylenediaminetetraacetic (EDTA), used in chemical cleaning and decontamination operations performed to clean steam generators, especially nuclear powered steam generators, is provided. The EDTA, metal and radionuclide-containing aqueous waste stream is, optionally, first treated to remove the metals and radionuclides. The pH of the resulting liquor is then adjusted to less than 2.0, causing the precipitation of acid EDTA. The solid acid EDTA is recovered for reuse or disposal, as desired. The remaining liquid is treated as required to permit environmental disposal. Removal of the metals and radionuclides can be by sulfide precipitation or ion exchange and may be conducted before or after precipitation of the acid EDTA.
Claims13
A process for treating a radionuclide contaminated aqueous stream containing a chelating agent and metal ions that has been used to chemically clean a component in a nuclear power plant, including the steps of:
- (1) adjusting the pH of the stream to a pH less than 2.0 to precipitate acid chelate from said stream;
- (2) recovering the acid chelate precipitate from the stream;
- (3) adjusting the pH of the stream to 7;
- (4) adding sulfide ions to the stream to form insoluble metal sulfides with the metal ions;
- (5) separating the insoluble metal sulfides formed in step (4) from the stream to produce a clear liquor;
- and
- (6) further processing said clear liquor so that said clear liquor is suitable for environmental disposal.
A process for treating a radionuclide contaminated aqueous waste solution containing EDTA and metal ions including the sequential steps of:
- (1) adjusting the pH of the waste solution to a pH sufficiently low to precipitate acid EDTA form said waste solution;
- (2) recovering the acid EDTA precipitate form the waste solution to produce a clear liquor;
- (3) adjusting the pH of the clear liquor to 7;
- (4) adding substantially exclusively sulfide ions to the waste stream solution to form insoluble metal sulfides with the metal ions;
- (5) separating the insoluble metal sulfides formed in the step (4) form the clear liquor to produce a final liquor;
- and
- (6) further processing said final liquor so that said final liquor is suitable for environmental disposal.
A process of treating a radionuclide contaminated aqueous waste solution containing EDTA and metal ions including the steps of:
- (1) adjusting the pH of the waste solution to a pH less than 2.0 to precipitate acid EDTA from said solution;
- (2) recovering the acid EDTA from waste solution to produce a clear liquor;
- (3) adjusting the pH of the clear liquor to 7;
- (4) removing the metal ions form the waste solution, and
- (5) further processing said liquor so that said final liquor is suitable for environmental disposal.
A process for recovering ethylenediaminetetra-acetic acid (EDTA) from the waste water produced by the EDTA chemical decontamination of a nuclear powered stream generator including the steps of:
- (1) adding substantially only sulfide ions to the waste water to remove metals and radionuclides from the waste water forming insoluble metal sulfides and a substantially metal and radionuclide-free liquor;
- (2) adjusting the pH of said liquor to a pH of less than 2.0, thereby causing the EDTA to precipitate out of said liquor as acid EDTA;
- (3) separating the acid EDTA precipitate from the liquor to form a final liquor and to recover the acid EDTA;
- (4) adjusting the pH of the said final liquor to 7;
- and
- (5) further processing said final liquor so that said final liquor is suitable for environmental disposal.
Dependencies are inferred from the claim text.