Highly attrition resistant mesoporous catalytic cracking catalysts
AssigneeExxon Research & Engineering Co.
InventorWilliam A. Wachter
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AssigneeExxon Research & Engineering Co.
InventorWilliam A. Wachter
Estimating the term…
A catalytic cracking catalyst for converting a hydrocarbon feedstock at elevated temperature in the substantial absence of hydrogen, into lower average molecular weight, lower boiling hydrocarbons useful as transportation fuels. The catalyst is a composite of a crystalline aluminosilicate zeolite in concentration ranging as high as about 80 percent, based on the total weight of the catalyst, within a mesoporous silica-alumina matrix. The matrix, preferably, is constituted of silica sols modified by alumina and clay and it is characterized as of polymodal pore size distribution, as measured by mercury porosimetry, a first mode wherein at least 75 percent, preferably about 80 percent to 90 percent, of the pore volume measured between 45 Angstroms and 2000 Angstroms is in pores greater than 160 Angstroms in diameter, and a second mode wherein up to about 20 percent of the pore diameters are greater than 100 Angstroms but less than 160 Angstroms in diameter. These catalysts are highly active, and selective in the production of olefins without high coke made. The attrition-resistance of these catalysts, as measured by the Davison Index, is quite low, ranging generally from about 1 to about 8, more generally from about 1 to about 5, or less.
A catalytic cracking catalyst for converting a hydrocarbon feedstock at elevated temperature in the substantial absence of hydrogen, into lower average molecular weight, lower boiling hydrocarbon transportation fuel which comprises
A catalytic cracking catalyst for converting a hydrocarbon feedstock at elevated temperature in the substantial absence of hydrogen, into lower average molecular weight, lower boiling hydrocarbon transportation fuel which comprises a crystalline aluminosilicate zeolite having a silica:alumina mole ratio greater than 2:1, and uniform pore diameters ranging from about 4 Angstroms to about 15 Angstroms in diameter, in concentration ranging from about 30 percent to about 60 percent, based on the total weight of the catalyst, a matrix comprised of silica and clay within which the crystalline aluminosilicate zeolite is dispersed, said matrix being characterized as porous and the pores as having a bimodal pore size distribution, as measured by mercury porosimetry, a first mode wherein from about 80 percent to about 90 percent of the pore volume measured between 45 Angstroms and 2000 Angstroms is in pores ranging from about 160 Angstroms in diameter to about 400 Angstroms in diameter, and a second mode wherein from about 5 percent to about 10 percent of the pores are of diameter ranging above about 100 Angstroms to about 160 Angstroms, and the attrition-resistance of the catalyst, as measured by the Davison Index ranges from about 1 to about 8,
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