Organic non-quaternary clathrate salts for petroleum separation
AssigneeExxon Research & Engineering Co.
InventorsDouglas R. Boate, Michael J. Zaworotko
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Abstract
Organic non-quaternary clathrate salts are useful for separating hydrocarbon feed streams into aromatics rich fraction and aromatics lean fraction. The organic non-quaternary clathrate salts are characterized by having cations containing less than 16 carbon atoms. Preferred salts are collidinium triflate and triethylammonium dihydroxybenzoate.
Claims10
A method for separating hydrocarbon feed streams containing mixtures of aromatic hydrocarbons and non-aromatic hydrocarbons into aromatics lean raffinate streams and aromatics rich extract streams by contacting the hydrocarbon feed streams with an organic non-quaternary clathrate salt having less than 16 carbon atoms in the cation, whereby the clathrate salt selectively interacts with the aromatic component of the hydrocarbon feed mixture producing a raffinate phase of reduced aromatic content a hydrocarbon - salt clathrate and an extract phase of increased aromatic content containing the clathrate salt and combined aromatic hydrocarbon, separating the raffinate phase from the extract phase and releasing the aromatic hydrocarbon from the clathrate salt of the extract phase to recover an aromatics rich stream and the organic non-quaternary salt which is recycled for contact with fresh hydrocarbon feed.
Dependencies are inferred from the claim text.