Polyester blends and their use in compostable products such as disposable diapers
AssigneeE. I. Du Pont de Nemours and Company
InventorsFrancis G. Gallagher, Hyunkook Shin, Raymond F. Tietz
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Abstract
The invention provides novel blends of starch with polyesters, and shaped articles of such blends, including fibers, foams and films, nonwovens from the fibers and disposable products such as diapers. The products are degradable under the conditions typically existing in waste composting processes, have low ingredient costs and yet provide strength and toughness properties adequate for end uses such as in disposable diapers. The polyesters are based upon polyethylene terephthalate copolymerized with other ingredients, including non-aromatic diacids, such as adipic and glutaric acids, polyethylene ether groups, such as diethylene glycol or higher polyalkylene glycols, and hydroxy acids.
Claims10
A fiber and film forming blend of starch, in amount by weight 1 to 80%, and of a polyester, in amount by weight 99 to 20%, wherein said polyester consists essentially of recurring structural units of the formulae:
- --[--C(O)--R--C(O)--OGO--].sub.a --[--C(O)--Q--O--].sub.b --
- wherein up to about 40 mole % of R is selected from the group consisting of a chemical bond and one or more divalent, non-aromatic, C.sub.1 -C.sub.10 hydrocarbylene radicals, and the remainder of R is at least about 85 mole % p-phenylene radical,
- wherein G is up to about 30 mole % of a polyethylene ether radical selected from the group consisting of
- --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 -- and --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --
- and the remainder of G is selected from the group consisting of polyalkylene ether radicals of molecular weight at least about 250, and --(CH.sub.2).sub.2 --, --(CH.sub.2).sub.3 --, and --(CH.sub.2).sub.4 -- radicals,
- wherein Q is derived from an hydroxy acid of formula
- HO[--C(O)--Q--O--].sub.x H,
- where x is an integer, such hydroxy acid having a melting point at least 5.degree. C. below its decomposition temperature, and Q is selected from the group consisting of a chemical bond and hydrocarbylene radicals --(CH.sub.2).sub.n --, where n is an integer from 1 to 5, --C(R')H--, and --C(R')HCH.sub.2 --, wherein R' is selected from the group of --CH.sub.3 and --CH.sub.2 CH.sub.3,
- and wherein "a" and "b" are mole fractions of the polymer, and the mole fraction "a" may be 0.6 to 1 and, correspondingly, mole fraction "b" may be 0 to 0.4,
- and wherein about 0.1 to about 15 mole % of the polymer contains alkali metal or alkaline earth metal sulfo groups.
Dependencies are inferred from the claim text.