Method of forming positive color image
AssigneeFuji Photo Film Co., Ltd.
InventorsShigeru Kuwashima, Akihiko Ikegawa
Life of this patent
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Abstract
A method of forming a direct positive color image by imagewise exposing a photographic material having at least one emulsion layer which contains previously non-fogged internal latent image-type silver halide grains, on a support, followed by color-developing the exposed material during or after fogging thereof, wherein the photographic material contains a color sensitizing dye and at least one compound or salt thereof which satisfies the condition-1 as defined in the specification. With the image formed by the method having an elevated maximum image density with a lowered minimum image density, and with the iamge-forming method displaying extremely excellent color reproducibility.
Claims8
A method of forming a direct positive color image comprising
- image-wise exposing a photographic material having at least one emulsion layer which contains previously non-fogged internal latent image-type silver halide grains on a support and then
- color-developing the exposed photographic material during or after fogging, wherein the photographic material contains (A) a color sensitizing dye and (B) at least one tricyclic or tetracyclic heterocyclic compound or salt thereof which satisfies the following condition-1:
- Condition-1:
- 2 ml of an aqueous solution of 4.0.times.10.sup.-4 mol/liter of anhydro-5,5'-dichloro-9-ethyl-3,3 '-bis(3-sulfo-propyl) thiacarbocyanine-hydroxide pyridinium salt and 1 ml of an aqueous solution of 1.0.times.10.sup.-1 mol/liter of potassium chloride are blended, and 4 ml of an aqueous solution of 8.0.times.10.sup.-2 mol/liter of the compound (B) to be added to the photographic material is added to the resulting blended solution, which is then diluted with water to make 10 ml;
- with the molecular extinction coefficient of the resulting aqueous solution at 624 nm being 1.0.times.10.sup.5 or less,
- wherein said tricyclic or tetracyclic heterocyclic compound comprises a structural formula selected from the following formulae:
- ##STR13## wherein said tricyclic or tetracyclic heterocyclic compound may be substituted by a halogen atom, --OM (in which M represents a hydrogen atom or a monovalent metal such as Na, K or Li), a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted amino group, a cyano group, a nitro group, a sulfo group, a carboxyl group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted acyl group, a substituted or unsubstituted aminosulfonyl group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted aryloxycarbonyl group, or a substituted or unsubstituted aminocarbonyl group.
Dependencies are inferred from the claim text.