Vattable and non-vattable quinoid dyes
AssigneeCiba-Geigy Corporation
InventorsJean-Marie Adam, Athanassios Tzikas
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AssigneeCiba-Geigy Corporation
InventorsJean-Marie Adam, Athanassios Tzikas
Estimating the term…
Dyes of the formula ##STR1## in which F is the radical of an indigoid dye, of a benzothioxanthene or of an aromatic dye which contains at least 4 alicyclic and/or heterocyclic, fused six-membered rings and at least two ring keto groups and is not water-soluble, R.sub.1 is a substituted or unsubstituted C.sub.1-4 -alkyl radical, a substituted or unsubstituted cycloalkyl radical, a substituted or unsubstituted aryl radical or a radical of the formula --A--Q where A is a substituted or unsubstituted C.sub.1-4 -alkylene radical and Q is a basic radical, which may be quaternised, and R.sub.2 is hydrogen or a substituted or unsubstituted C.sub.1-4 -alkyl radical, or in which R.sub.1 and R.sub.2 together with the ##STR2## group are a phthalimide radical, and R.sub.3 is hydrogen, a substituted or unsubstituted C.sub.1-4 -alkyl radical, a substituted or unsubstituted aryl radical, a C.sub.1-4 -alkoxycarbonyl radical or a N,N-di-C.sub.1-4 -alkylcarboxamide radical and n is 1, 2, 3 or 4. The novel dyes are suitable as vat dyes for dyeing natural or regenerated cellulose and as cationic dyes for dyeing paper.
A dye of the formula ##STR57## in which F is a group of a dibenzanthrone, isodibenzanthrone, 16,17-ethylenedioxydibenzanthrone, 2,2'-dibenzanthronyl, 2,2'-bisindolindigo, 2,2'-bisthionaphtheneindigo, cis- or trans-naphthoylenebenzimidazole, benzothioxanthene, N,N'-di-p-tolyl-perylenetetracarboxylic acid diimide, N,N'-di-p-phenethoxynaphthalene-1,4,5,8-tetracarboxylic acid diimide, 5,5'-bisnaphthyl-1,1',8,8'-tetracarboxylic acid-dibenzimidazole, 5,5'-bis-naphthyl-1,1',8,8'-tetracarboxylic acid-6",6"'-dimethyldibenzimidazole, 5,5'-bisnaphthyl-1,1',8,8'-tetracarboxylic acid-5",5"',6",6"'-tetramethoxydibenzimidazole or 16,17-methylenedioxydibenzanthrone dye, or a group of a compound of the formula ##STR58## R.sub.1 is a group of the formula --A--Q wherein A is methylene and Q is ##STR59## n is 1 or 2, and R.sub.2 and R.sub.3 are hydrogen.
Dependencies are inferred from the claim text.