Catalyzed hydrocarbyllithium process
AssigneeFMC Corporation
InventorsRobert C. Morrison, Randy W. Hall, James A. Schwindeman, Conrad W. Kamienski, John F. Engel
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AssigneeFMC Corporation
InventorsRobert C. Morrison, Randy W. Hall, James A. Schwindeman, Conrad W. Kamienski, John F. Engel
Estimating the term…
A catalytic process for alkylating an alkali metal selected from lithium, sodium and potassium with an alkyl halide containing 3 to 20 carbon atoms comprising conducting the reaction in the presence of a catalytic compound represented by the formula (RR.sup.1 R.sup.2 M.sup.a)yA(R.sup.3)x wherein R, R.sup.1 and R.sup.2 are independently selected from hydrogen, halogen, alkyl, alkenyl, cycloalkyl, and aryl groups, R.sup.3 is independently selected from aryl groups containing 6 to 18 carbon atoms, four to six-membered heterocyclic carbon containing groups containing one to two hetero atoms selected from oxygen, nitrogen, and sulfur; hydroxyalkyl, alkoxyalkyl and monoalkylaminoalkyl and dialkylaminoalkyl groups containing 2 to 13 carbon atoms; M.sup.a is selected from silicon, carbon, germanium, and tin, A is selected from oxygen, sulfur, nitrogen and phosphorus, and x and y independently have values from zero to three.
A process for alkylating an alkali metal selected from lithium, sodium and potassium with an alkyl halide containing 3 to 20 carbon atoms in which the improvement comprises conducting the reaction in a hydrocarbon solvent in the presence of a catalyst compound represented by the formula
A process of producing an alkyllithium by reacting lithium with a hindered alkyl chloride in which the hindered alkyl group is selected from t-butyl, and 2-ethylhexyl groups in which the improvement comprises conducting the reaction in the presence of 0.02 to 5.0 mole percent of a compound selected from hydrocarbyl ethers containing 2 to 16 carbon atoms in a hydrocarbon solvent.
Dependencies are inferred from the claim text.