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US 5,210,360 AGranted
Ethylene oligomerization
AssigneePhillips Petroleum Company
InventorAn-hsiang Wu
Life of this patent
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Abstract
An ethylene oligomerization catalyst system is provided that is produced by the process consisting essentially of: contacting an organonickel compound, an aromatic acid compound, and a phosphine compound. Additionally, an ethylene oligomerization process is provided that consists essentially of oligomerizing ethylene with the above-mentioned oligomerization catalyst system.
Claims13
An ethylene oligomerization process consisting essentially of:
- oligomerizing ethylene under oligomerization conditions with an oligomerization catalyst system produced by the process consisting essentially of contacting an organonickel compound, an aromatic acid compound, a phosphine compound;
- wherein the nickel component is in the zero valence state or can undergo reduction to the zero valence state, and the organic component is an unsaturated organic group;
- and
- wherein said aromatic acid compound has the following formula ##STR2## wherein each R is independently selected from the group consisting of hydrogen, and hydroxyl (-OH), provided that, at least one R is not hydrogen;
- and
- wherein said phosphine compound has the formula PR.sub.3, wherein each R is independently selected from the group consisting of hydrogen and hydrocarbyl radicals, provided that said hydrocarbyl radical has 1 to about 20 carbon atoms and that any alkenyl substitution be at least 3 carbon atoms removed from the phosphorous atom and at least one R is not a hydrogen;
3 more elements
An ethylene oligomerization process consisting essentially of:
- oligomerizing ethylene under oligomerization conditions with an oligomerization catalyst system produced by the process consisting essentially of contacting bis(1,5-cyclooctadiene)nickel, phenol, and dicyclohexylphosphine.
Dependencies are inferred from the claim text.