Heterocyclic 1,2-difluorobenzene derivatives
AssigneeMerck Patent GmbH
InventorsVolker Reiffenrath, Joachim Krause, Andreas Wachtler, Thomas Geelhaar
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AssigneeMerck Patent GmbH
InventorsVolker Reiffenrath, Joachim Krause, Andreas Wachtler, Thomas Geelhaar
Estimating the term…
Heterocyclic 1,2-difluorobenzene derivatives of the formula I ##STR1## in which R.sup.1 and R.sup.2, in each case independently of one another, are an alkyl groups (sic) having 1-15 C atoms in which, in addition, one or more CH.sub.2 groups may be replaced by a divalent radical selected from the group comprising --O--, --S--, --CO--, --O--CO--, --CO--O--, --CH.dbd.CH-- and --C.tbd.C--, where two heteroatoms are not linked directly to one another, A.sup.1 and A.sup.2, in each case independently of one another, are a 1,4-phenylene group which is unsubstituted or monosubstituted or polysubstituted by fluorine, and in which, in addition, one or two CH groups may be replaced by N, or are a 1,3,4-thiadiazole-2,5-diyl group or a trans-1,4-cyclohexylene group, m and n are each 0 or 2, o is 0 or 1, and p is 0, 1 or 2, where (o+p) is 1, 2 or 3 and, in the case where p=2, the A.sup.2 groups and n may be identical or different with the proviso that at least one of the groups A.sup.1 and A.sup.2 is a 1,3,4-thiadiazole-2,5-diyl group or an unsubstituted or substituted 1,4-phenylene group in which one or two CH groups have been replaced by N, are suitable as components of liquid-crystalline phases.
A heterocyclic 1,2-difluorobenzene derivative of the formula I2 ##STR11## in which R is a straight chain alkyl group having 1 to 15 C atoms in which, in addition, one or more CH.sub.2 may be replaced by a divalent radical selected from --O--, --S--, --CO--, --O--CO--, --CO--O--, --CH.dbd.CH-- or --C.tbd.C--, where two heteroatoms are not linked directly to one another, P is 1 or 2, n is 0 or 2,
A difluorobenzene derivative of claim 6, of the formulae having the ##STR12## wherein R is, in each case independently of one another, straight-chain or monobranched alkyl having 3 to 12 C atoms in which, in addition, one CH.sub.2 group which is not linked to 0 may be replaced by --O-- or --CH.dbd.CH--.
Dependencies are inferred from the claim text.