Organopolysiloxanes with polyether and ester groups linked to a common spacer group
AssigneeTh. Goldschmidt AG
InventorsDietmar Schaefer, Andreas Weier, Dietmar Wewers
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Abstract
Organopolysiloxanes having polyether and ester groups linked to a common spacer group, wherein the spacer group is linked through an SiC bond to the siloxane backbone and a method for the synthesis thereof are disclosed. These compounds are useful as additives for plastics, lacquers and binders for reducing the coefficient of sliding friction, for improving scratch resistance and increasing abhesiveness. If the compounds are esters of acrylic or methacrylic acid, they can be used as radiation-curable lacquers and coating compositions.
Claims14
An organopolysiloxane having polyether and ester groups linked to a common spacer group, wherein the spacer group is linked to the siloxane backbone through an SiC bond and the organopolysiloxane has the formula ##STR25## wherein R.sup.1 groups are the same or different and in each case represent alkyl groups with 1 to 4 carbon atoms or phenyl groups, with the proviso that at least 90% of the R.sup.1 groups are methyl groups,
- R.sup.2 is selected from the group consisting of R.sup.1 group, R.sup.3 --R.sup.4 group, an alkyl group with 2 to 30 carbon atoms and a hydrogen group, wherein the ratio of R.sup.3 --R.sup.4 group to the sum of alkyl group with 2 to 30 carbon atoms and hydrogen group is 70:30 to 100:0, in which
- R.sup.3 is a divalent hydrocarbon group, the carbon chain of which is selected from the group consisting of a carbon chain, a carbon chain interrupted by an oxygen atom and a carbon chain with a carbonyl group and
- R.sup.4 is one of the following groups:
- ##STR26## in which R.sup.5 is the acyl group of a monocarboxylic acid with 1 to 20 carbon atoms,
- R.sup.6 is a polyether group and
- R.sup.7 is a hydrogen or methyl group and
- a has a value of 1 to 1,000 and
- b has a value of 0 to 10,
- with the proviso that, in the average molecule, at least one R.sup.2 group is a group having the formula R.sup.3 --R.sup.4.
Dependencies are inferred from the claim text.