Process for preparing a vanadium-based catalyst suitable for olefin polymerization
AssigneeBP Chemicals Limited
InventorJean-Claude A. Bailly
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Abstract
The present invention relates to a process for preparing a Ziegler-Natta type catalyst based on a vanadium compound precipitated on a MgCl.sub.2 spherical support. The catalyst preparation consists of contacting within a liquid hydrocarbon a vanadium-reducing agent chosen from organometallic compound with a vanadium compound soluble in the liquid hydrocarbon at least one halogen and one alkoxy group, and with a support containing (i) MgCl.sub.2 free from Mg--C bond and (ii) an organic electron donor compound free from labile hydrogen. The support consists of spherical particles having a well-defined diameter and a narrow particle size distribution. The catalyst is particularly suitable for manufacturing in a gas process elastomeric copolymers of propylene.
Claims21
A process for preparing an elastomeric copolymer of propylene with ethylene and/or 1-butene having a propylene content by weight of 30 to 72% and obtaining said elastomeric copolymer directly in the form of a non-adhesive powder with a high yield, which process comprises copolymerising in a gas phase reactor propylene with ethylene and/or 1-butene at a temperature from 0.degree. to 60.degree. C. under a total pressure from 0.1 to 5 MPa in the presence of (i) a catalyst based on a vanadium compound precipitated within a liquid hydrocarbon by reduction reaction of vanadium on a spherical support of magnesium dichloride and (ii) an organoaluminum compound cocatalyst, said catalyst being prepared by contacting with said liquid hydrocarbon:
- (a) a vanadium-reducing agent selected from the group consisting of organoaluminum, organomagnesium or organozinc compounds with,
- (b) a vanadium compound soluble in said liquid hydrocarbon and containing halogen atom, X, and alkoxy group, OR, in a molar ratio X:OR, from 0.051 to 20:1, and
- (c) a solid support consisting of spherical particles and containing (i) from 80 to 99.5 mol % of magnesium dichloride substantially free from any product containing a Mg--C bond, and (ii) from 0.5 to 20 mol % of at least one organic electron-donor compound, D, free from labile hydrogen.
Dependencies are inferred from the claim text.