Amine salts of sulfur-containing alkylated phenols or alkylated naphthols as multifunctional antioxidant and antiwear additives
AssigneeMobil Oil Corporation
InventorsShih-Ying Hsu, Arjun K. Goyal, Andrew G. Horodysky, Liwen Wei
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Abstract
Amine salts of sulfur-containing alkylated phenols or alkylated naphthols, have been found to be effective multifunctional antioxidant and antiwear additives for lubricants.
Claims18
An improved lubricant composition comprising a major proportion of said lubricant or fuel and a minor multifunctional antiwear, antioxidant proportion of an additive product of reaction comprising an amine salt of a sulfur-containing hydrocarbyl phenol or naphthol prepared from (1) the reaction of a hydrocarbyl phenol or naphthol and a quaternary ammonium salt in the presence of an organic or inorganic base and a protic or aprotic solvent and (2) thereafter reacting in situ the resulting phenol-naphthol quaternary ammonium complex and elemental sulfur in a non-sulfur reactive solvent at temperatures varying from about 25.degree. to about 300.degree. C., pressures varying from ambient to slightly higher or autogenous for a time sufficient to obtain the desired tetra-substituted ammonium salt of sulfurized hydrocarbyl phenol or naphthol.
A process of preparing a multifunctional antioxidant, antiwear additive product by (1) the reaction of a hydrocarbyl phenol or naphthol and a quaternary ammonium salt in the presence of an organic or inorganic base and a protic or aprotic solvent and (2) thereafter reacting in situ the resulting phenol-quaternary ammonium complex and elemental sulfur in a non-sulfur reactive solvent in substantially equimolar, less than molar or more than molar ratios at temperatures varying from about 25.degree. C. to about 300.degree. C., pressure varying from ambient to slightly higher or autogenous for a time sufficient to obtain the desired tetra-substituted ammonium salt of sulfurized hydrocarbyl phenol or naphthol.
Dependencies are inferred from the claim text.