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US 5,206,315 AGranted
Process for polymerizing 1-olefins and catalyst therefor
AssigneePhillips Petroleum Company
InventorPhil M. Stricklen
Life of this patent
Estimating the term…
Abstract
A process for preparing polymers of 1-olefins and a catalyst for such process are provided. The catalyst is comprised of a solid titanium halide-containing compound and an alkylaluminum hydride.
Claims10
A process for preparing a polymer of 1-olefin monomer comprising polymerizing said monomer in contact with a two-component catalyst, the first component being comprised of a solid titanium trichloride complex having the formula
- TiCl.sub.3 (AlR.sub.n X.sub.3-n).sub.x (C).sub.y
- wherein
- R is a hydrocarbon radical containing from 1 to 18 carbon atoms,
- X is a halogen,
- n is a number from 0 to 2,
- C is an organic complexing agent selected from compounds having the formula
- R'-O-R", R'-S-R" and R'-SH
- wherein R' and R" are independently hydrocarbon radicals containing from 1 to 15 carbon atoms,
- x is a number less than 0.3, and
- y is a number higher than 0.001, and the second component being comprised of an alkylaluminum hydride of the formula
- AlR'".sub.m H.sub.3-m
- wherein
- R'" is a hydrocarbon radical containing from 1 to 18 carbon atoms, and
- m is a number from 1 to 2.
11 more elements
A process for polymerizing 4-methyl-1-pentene monomer comprising polymerizing said monomer in contact with a two-component catalyst,
- the first catalyst component being comprised of a solid titanium trichloride complex having the formula
- TiCl.sub.3 (AlR.sub.n X.sub.3-n).sub.x (C).sub.x
- wherein
- R is a hydrocarbon radical containing from 2 to 6 carbon atoms,
- X is chlorine,
- n is 2,
- C is an organic complexing agent having the formula
- R'-O-R"
- wherein
- R' and R" are identical alkyl radicals containing from 2 to 8 carbon atoms,
- x is a number less than 0.2, and
- y is a number exceeding 0.009;
- and
- the second catalyst component being diethylaluminum hydride.
11 more elements
Dependencies are inferred from the claim text.