Photoelectrographic elements utilizing nonionic sulfonic acid photogenerators
AssigneeEastman Kodak Company
InventorsDouglas E. Bugner, Jeanne E. Kaeding, Michel F. Molaire
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Abstract
The present invention relates to a photoelectrographic element having a conductive layer in electrical contact with an acid photogenerating layer which is free of photopolymerizable materials and contains an electrically insulating binder and a nonionic sulfonic acid photogenerator. A method of forming images with this element is also disclosed.
Claims22
A photoelectrographic element for electrostatic imaging which is capable of producing multiple prints from a single exposure and exhibiting consistent performance at variable relative humidities, said element comprising:
- a conductive layer in electrical contact with an acid photogenerating layer which is free of photopolymerizable materials and comprises an electrically insulating binder and a nonionic sulfonic acid photogenerator.
A photoelectrographic method for printing using a photoelectrographic element comprising a conductive layer in electrical contact with an acid photogenerating layer which is free of photopolymerizable materials and comprises an electrically insulating binder and a nonionic sulfonic acid photogenerator and exhibits consistent performance at variable relative humidities, said method comprising:
- exposing the acid photogenerating layer imagewise to radiation without prior charging to create a permanent latent conductivity pattern and
- printing an image from the latent conductivity pattern, said printing comprising:
- charging said element with the acid photogenerating layer having a latent conductivity pattern to create a electrostatic latent image;
- developing the electrostatic latent image by applying charged toner particles to said element to produce a toned image;
- and
- transferring the toned image to a suitable receiver, wherein said printing is carried out one time for each print made.
A photoelectrographic element for electrostatic imaging which exhibits consistent performance at variable relative humidities comprising a conductive layer in electrical contact with an acid photogenerating layer which is free of photopolymerizable materials and comprises:
- an electrically insulating binder selected from the group consisting of polycarbonates, polyesters, polyolefins, phenolic resins, paraffins, mineral waxes and aromatic esters of a poly(vinyl alcohol) polymer;
- a nonionic sulfonic acid photogenerator selected from the group consisting of the sulfonate esters of the N-hydroxyamides and N-hydroxyimides;
- and
- a near-ultraviolet radiation absorbing sensitizer selected from the group consisting of xanthones, indandiones, indanones, throxanthones, acetophenones, benzophenones, anthracenes, dialkoxyanthracenes, perylenes, phenothiazines, and pyrenes;
- wherein said element has a .DELTA.Fm value less than about 0.10.
Dependencies are inferred from the claim text.