Lubricants containing aryl arenesulfonates as lubricity additives
AssigneeThe Dow Chemical Company
InventorBassam S. Nader
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Abstract
A lubricating composition which comprises a lubricating fluid and an aryl arenesulfonate in an amount sufficient to increase the lubricity of the lubricating fluid. A process for increasing the lubricity of a lubricating fluid which comprises adding an aryl arenesulfonate to the lubricating fluid in an amount greater than or equal to about 0.5 percent and less than or equal to about 5 percent based on the weight of the lubricating fluid.
Claims40
A lubricating composition which comprises a lubricating fluid and an aryl arenesulfonate in an amount sufficient to increase the lubricity of the lubricating fluid, wherein the aryl arenesulfonate is of the formula ASO.sub.3 A, ASO.sub.3 BSO.sub.3 A, or (ASO.sub.3).sub.3 B wherein A is independently in each occurrence phenyl or substituted phenyl, wherein when A is substituted phenyl the phenyl can be substituted by halo, keto, alkyl of up to 10 carbons, polyhaloalkyl, alkoxy, polyhaloalkoxy, aryl, polyhaloaryl, aryloxy, polyhaloaryloxy, polyhaloalkylaryl, or polyhaloaryloxy, and wherein B is benzene or two benzene rings connected by a divalent bridging group selected from the group consisting of C(CH.sub.3).sub.2, O, OCH.sub.2, OCH.sub.2 CH.sub.2, OCH.sub.2 CH.sub.2 O, C(CF.sub.3).sub.2, S, SO.sub.2, CO, and 9,9'-fluorene.
A process for increasing the lubricity of a lubricating fluid which comprises adding an aryl arenesulfonate to the lubricating fluid in an amount greater than or equal to about 0.5 percent and less than or equal to about 5 percent based on the weight of the lubricating fluid, wherein the aryl arenesulfonate is of the formula ASO.sub.3 A, ASO.sub.3 BSO.sub.3 A, or (ASO.sub.3).sub.3 B wherein A is independently in each occurrence phenyl or substituted phenyl, wherein when A is substituted phenyl the phenyl can be substituted by halo, keto, alkyl of up to 10 carbons, polyhaloalkyl, alkoxy, polyhaloalkoxy, aryl, polyhaloaryl, aryloxy, polyhaloaryloxy, polyhaloalkylaryl, or polyhaloaryloxy, and wherein B is benzene or two benzene rings connected by a divalent bridging group selected from the group consisting of C(CH.sub.3).sub.2, O, OCH.sub.2, OCH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 O, C(CF.sub.3).sub.2, S, SO.sub.2, CO, and 9,9'-fluorene.
Dependencies are inferred from the claim text.