Aqueous antioxidant emulsions
AssigneeCiba-Geigy Corporation
InventorsHans Mollet, Martin Holer
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AssigneeCiba-Geigy Corporation
InventorsHans Mollet, Martin Holer
Estimating the term…
Storage-stable, non-sedimenting emulsions comprising a) 10 to 80% by weight, based on the emulsion, of one or more anti-oxidants, b) 0.25 to 10% by weight, based on the emulsion, of a surfactant in the form of a fatty acid salt of formula R-COOY, wherein R is straight chain or branched C.sub.3 -C.sub.18 alkyl or straight chain or branched C.sub.3 -C.sub.18 -alkenyl, or is phenyl(C.sub.3 -C.sub.18)alkyl, and Y is an alkali metal, which salt is prepared in situ from the fatty acid, c) 0.25 to 10% by weight, based on the emulsion, of a co-surfactant in the form of an alcohol of the general formula R'--OH, wherein R' is straight chain or branched C.sub.4 -C.sub.19 alkyl or straight chain or branched C.sub.4 -C.sub.19 alkenyl, or is phenyl(C.sub.4 -C.sub.19)alkyl, and d) water to make up 100%. The emulsions are used for stabilizing emulsion-polymerized polymers and copolymers such as ABS.
A storage-stable, non-sedimenting emulsion comprising
A process for the preparation of an aqueous, storage-stable, non-sedimenting antioxidant emulsion 1, which comprises heating the antioxidant or mixture of antioxidants, which are liquid or liquefied by heating, with an acid of the general formula R--COOH, wherein R is straight chain or branched C.sub.3 -C.sub.18 alkyl or straight chain or branched C.sub.3 -C.sub.18 alkenyl or phenyl(C.sub.3 -C.sub.18)alkyl, and with an alcohol of the general formula R'--OH, wherein R' is straight chain or branched C.sub.4 -C.sub.19 alkyl or straight chain or branched C.sub.4 -C.sub.19 alkenyl or phenyl(C.sub.4 -C.sub.19)alkyl, and subsequently adding an aqueous solution of an alkali metal hydroxide, alkali metal hydrogencarbonate or alkali metal carbonate to the melt until the acid is neutralized, and, optionally adding water to dilute the emulsion.
Dependencies are inferred from the claim text.