Catalytic production of aryl alkyl hydroperoxides by manganese complexes
AssigneeExxon Research & Engineering Co.
InventorsRobert T. Stibrany, Sergiu M. Gorun
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Abstract
This invention relates to a process for preparing organic hydroperoxides by selectively oxidizing aryl alkyl hydrocarbons to their corresponding organic hydroperoxides using a catalyst certain tetranuclear manganese complexes. The process is carried out without appreciable decomposition by the catalyst of the resulting organic hydroperoxides, and without oxidation by the catalyst of other hydrocarbons present in the starting mixture. The process of the present invention is useful for producing organic hydroperoxides, which themselves are useful as starting materials for a number of commercial reactions, for example, phenol and acetone production.
Claims9
A process for preparing organic hydroperoxides by selectively converting aryl alkyl hydrocarbons to the corresponding organic hydroperoxides, comprising:
- contacting aryl alkyl hydrocarbons wherein the aryl alkyl hydrocarbons contain a benzylic hydrogen of the general formula:
- ##STR3## wherein R.sub.1 and R.sub.2 may be organo groups or hydrogen groups and may be the same or different from each other with an oxygen-containing gas and a catalytically effective amount of a tetranuclear manganese complex catalyst having the formula:
- M.sub.2 [Mn.sub.4 (O)(OH)(O.sub.2 CR).sub.2 L.sub.2 ]
- wherein M is an alkali metal or an alkaline earth metal, R is selected from the group consisting of hydrogen and a hydrocarbyl group and L is a ligand having the formula:
- ##STR4## to produce the corresponding organic hydroperoxides.
A process for preparing organic hydroperoxides from a mixture of hydrocarbons, comprising selectively converting aryl alkyl hydrocarbons, wherein the aryl alkyl hydrocarbons contain a benzylic hydrogen of the general formula:
- ##STR5## wherein R.sub.1 and R.sub.2 may be organo groups or hydrogen groups and may be the same or different from each other, in a mixture of hydrocarbons by contacting said hydrocarbons with an oxygen-containing gas and a catalytically effective amount of a tetranuclear manganese complex catalyst having the formula:
- M.sub.2 [Mn.sub.4 (O)(OH)(O.sub.2 CR).sub.2 L.sub.2 ]
- wherein M is an alkali metal or an alkaline earth metal, R is selected from the group consisting of hydrogen and a hydrocarbyl group and L is a ligand having the formula:
- ##STR6## to produce the corresponding organic hydroperoxides.
Dependencies are inferred from the claim text.