Process for preparing primary hydroxyl-containing diols
AssigneeTexaco Chemical Company
InventorsMichael Cuscurida, George P. Speranza
Life of this patent
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Abstract
The invention concerns a method for the preparation of polyurethane, polyester, polyamide, and polyurea diols which contain essentially all primary hydroxyl groups without capping by ethylene oxide. The method comprises coupling an alkylene oxide adduct of propylene glycol t-butyl ether or butylene glycol t-butyl ether or its aminated derivative with organic diisocyanates or dibasic acids followed by cleavage of the t-butyl group with an acid catalyst. The resulting diol is useful in many types of urethane applications including foams, elastomers and coatings.
Claims6
A method for preparing diols which contain essentially all primary hydroxyl groups comprising reaction of ethylene oxide, propylene oxide and/or butylene oxide with ethylene, propylene or butylene glycol t-butyl ether, then coupling these reaction products with organic diisocyanates, dibasic acids, or dibasic esters followed by cleavage of the t-butyl group with an acid catalyst.
A method for preparing diols which contain essentially all primary hydroxyl groups comprising reacting ethylene oxide, propylene oxide and/or butylene oxide with ethylene, propylene or butylene glycol t-butyl ether, then aminating this product and coupling these aminated reaction products with organic diisocyanates or dibasic acids followed by cleavage of the t-butyl group with an acid catalyst.
Dependencies are inferred from the claim text.