Thermosettable powder compositions of polymaleimide and allyl-functional prepolymer
AssigneeFord Motor Company
InventorMohinder S. Chattha
Life of this patent
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Abstract
This invention is directed to a shelf-stable, powder composition adapted to form a high T.sub.g, thermally stable, impact resistant thermoset material. The composition consists essentially of a mixture of an allyl-functional prepolymer component and polymaleimide component. The allyl-functional prepolymer component is the reaction product of an aromatic allyl-functional compound and a modifying compound wherein the compounds contain mutually reactive funtionalities such as an aromatic allyl-functional epoxide compound and a modifying amine compound.
Claims6
A shelf stable, powder composition adapted to form a high T.sub.g, thermally stable, impact resistant thermoset material, which composition consists essentially of an intimate mixture of two components:
- (A) an allyl-functional prepolymer component:
- (i) having a number average molecular weight between about 300 and about 3000 and (ii) being the reaction product of:
- (a) an aromatic allyl-functional compound additionally containing a first reactive functionality;
- and
- (b) a modifying compound containing a second reactive functionality capable of reacting with said first reactive functionality of compound (a), said first reactive functionality and said second reactive functionality being selected from the following reactive functionality pair:
- epoxide and amine, said compound (a) and compound (b) being reacted in an amount sufficient to react substantially all of said amine and epoxide functionalities which may be present on said compound (a) and compound (b);
- and
- (B) polymaleimide component,
- said allyl-functional prepolymer component and said polymaleimide component being present in said composition in amounts sufficient to provide between about 0.8 and 1.2 maleimide groups of said polymaleimide component for each allyl group present on said allyl-functional prepolymer component.
A method for forming a high T.sub.g, thermally stable, impact resistant thermoset material, which method comprises:
- reacting at a temperature between about 100.degree. C. and about 270.degree. C. a composition which consists essentially of an intimate mixture of two components:
- (A) an allyl-functional prepolymer component:
- (i) having a number average molecular weight between about 300 and about 3000 and (ii) being the reaction product of:
- (a) an aromatic allyl-functional compound additionally containing a first reactive functionality;
- and
- (b) a modifying compound containing a second reactive functionality capable of reacting with said first reactive functionality of compound (a), said first reactive functionality and said second reactive functionality being selected from the following reactive functionality pair:
- epoxide and amine, compound (a) and compound (b) being reacted in an amount sufficient to react substantially all of the amine and epoxide functionalities which may be present on said compound (a) and said compound (b);
- and
- (B) polymaleimide component, in such molar proportion that for each allyl group present on said allyl-functional prepolymer component (A) there are between about 0.8 and about 1.2 maleimide groups of said polymaleimide component (B).
Dependencies are inferred from the claim text.