Method for the preparation of highly elastic forms of reduced compression hardness having polyurethane groups
AssigneeTh. Goldschmidt AG
InventorsVolker Mohring, Volker Zellmer
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Abstract
A method for the preparation of highly elastic foams of reduced compression hardness and having urethane groups is disclosed, in which the reaction of the polyurethane-forming materials is carried in the presence of 0.01 to 5% by weight, based on the polyol, of a compound, which has at least one polyoxyalkylene group and at least one anionic group in the molecule. The use of fluorocarbons to decrease the compression hardness can reduced appreciably by the use of this compound.
Claims7
A method for the preparation of highly elastic polyurethane foams of reduced compression hardness by the reaction of polyisocyanate with polyether having a molecular weight of 400 to 10,000 and containing at least two hydroxyl groups in the presence of cross-linking agent, catalyst and water and optionally in the presence of emulsifier, stabilizer and organic blowing agent, comprising carrying out the reaction of the polyurethane-forming components in the presence of a compound Y which contains at least one polyoxyalkylene group and at least one group A.sup.- M.sup.30 in the molecule, wherein A is an anionic group selected from the group consisting of --SO.sub.3, --CH.sub.2 CH.sub.2 --SO.sub.3, --(CH.sub.2).sub.3 --SO.sub.3, --CH.sub.2 --CH(CH.sub.3)--CH.sub.2 --SO.sub.3, --CH.sub.2 --CH(OH)--CH.sub.2 --SO.sub.3, --CH.sub.2 --CH(OH)--CH.sub.2 --S.sub.2 O.sub.3, --Z--COO-- with Z being a divalent, optionally substituted hydrocarbon group, --CO--Z--COO--, PO.sub.3, PO.sub.2, --CH.sub.2 ).sub.n --PO.sub.3, --CH.sub.2).sub.n --PO.sub.2, with n=1, 2, 3 or 4, and wherein
- M is a cation selected from the group consisting of alkali metal, alkaline earth metal, Mn, Fe, Co, Ni, Cu, Zn, Al, NH.sub.4,
- in an amount of 0.01 to 5% by weight, based on the weight of the polyether.
Dependencies are inferred from the claim text.