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US 5,183,796 AGranted
Catalyst for metathetic reactions of hydrocarbons and method for forming the catalyst
AssigneeNeste Oy
InventorsPekka Knuuttila, Eeva-Liisa Lakomaa
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AssigneeNeste Oy
InventorsPekka Knuuttila, Eeva-Liisa Lakomaa
Estimating the term…
The present invention concerns a heterogenic catalyst suited to the metathesis reactions of hydrocarbons in particular. Such a catalyst includes an inorganic oxide support, typically consisting of .gamma.-alumina, having rhenium oxide absorbed onto its surface. The catalyst in accordance with the invention is prepared by vapourizing a precursor of rhenium, preferably rhenium heptoxide, preferably at a temperature of at least 160.degree. C., and routing the vapour into a reaction chamber where they are brought to interaction with the support material. The temperature of the support material is kept above the condensation temperature of the vapour and simultaneously sufficiently high so as to attain the thermal activation energy level necessary for the generation of bonds between the rhenium oxide and the support material. According to the invention, the process is carried out preferredly within a temperature range of approx. 160.degree. . . . 500.degree. C. The rhenium oxide precursor is introduced in vapour phase in an amount, which is at least equal to or, preferably, in excess of the number of available binding sites on the support material surface. The activity of a catalyst even with a very low content of catalytic metal species is as high as the activity of a catalyst of appreciably higher content of rhenium that has been prepared by the methods of conventional technology.
A heterogenic catalyst particularly suited for liquid- or vapour-phase metathetic reactions of hydrocarbons, said catalyst containing rhenium oxide bound onto an inorganic support material, wherein said catalyst is prepared by a method comprising the steps of:
The catalyst in accordance with claim 9, wherein the posttreatment is performed by heating in the presence of air, water vapour, hydrocarbon or an inert gas.
A method for forming a heterogenic catalyst particularly suited for liquid- or vapour-phase metathetic reactions of hydrocarbons, said catalyst containing a rhenium oxide bound onto an inorganic support material, wherein said method comprises the steps of:
A method for forming a heterogenic catalyst particularly suited for liquid- or vapour-phase metathetic reactions of hydrocarbons, said catalyst containing a rhenium oxide bound onto tan inorganic support material, wherein said method comprises the steps of:
Dependencies are inferred from the claim text.