Decontamination of radioactive metals
AssigneeWestinghouse Electric Corp.
InventorsThomas S. Snyder, William R. Gass, Samuel A. Worcester, Laura J. Ayers, Gregory F. Boris
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Abstract
Technetium is separated from nickel by electro-refining contaminated nickel. Electrorefining controls the electrolyte solution oxidation potential to selectively reduce the technetium from the metallic feedstock solution from Tc(VII) to Tc(IV) forcing it to report to the anodic slimes and thereby preventing it from reporting to the cathodic metal product. This method eliminates the need for peripheral decontamination processes such as solvent extraction to remove the technetium prior to nickel electrorefining. These methods are particularly useful for remediating nickel contaminated by radio-contaminants such as technetium and actinides.
Claims20
A method of extracting technetium from radiocontaminated metal, comprising the steps of:
- dissolving metal contaminated with radioactive technetium in an aqueous solution to produce a solution containing pertechnetate ions and metal ions;
- reducing the pertechnetate ions to a technetium oxide precipitate;
- and
- cathodically depositing metal from the solution.
Dependencies are inferred from the claim text.