Emulsion pressure-sensitive adhesive polymers in bandage and medical tape constructions
AssigneeAvery Dennison Corporation
InventorMargaret M. Bernard
Life of this patent
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Abstract
Inherently tacky, emulsion pressure-sensitive adhesive polymers comprising about 35 to about 65 percent by weight alkyl acrylates, about 15 to about 35 percent vinyl esters, about 20 to about 35 percent by weight diesters of a dicarboxylic acid, and up to about 5 percent by weight of an unsaturated carboxylic acid formed in the presence of a reactive surfactant and having a gel content of about 50 to 70 percent by weight as formed are used in sterilizable bandage and medical tape constructions.
Claims20
A combination for use as a medical tape or bandage construction, said combination comprising:
- (a) a sterilizable backing;
- (b) a sterilizable inherently tacky, pressure-sensitive adhesive polymer applied to one side of said backing, said adhesive formed by emulsion polymerization and comprising on a polymerized basis and based on the total weight of the monomers:
- (i) at least one alkyl acrylate containing from about 4 to about 8 carbon atoms in the alkyl group, the total amount of alkyl acrylate present being from about 35 to about 60 percent by weight;
- (ii) at least one vinyl ester containing from 2 to about 16 carbon atoms in the alkyl group of the acid, the total amount of the vinyl ester present being from 15 to about 35 percent by weight;
- (iii) at least one diester of a dicarboxylic acid in which each alkyl group of the diester independently contains from about 6 to about 12 carbon atoms, the total of the diesters present being in amount from about 20 to about 40 percent by weight;
- and
- (iv) at least one unsaturated carboxylic acid containing from about 3 to about 5 carbon atoms, present in the total of the unsaturated carboxylic acid in an amount up to about 5 percent by weight, said polymer being formed in the presence of a reactive surfactant which is a vinyl functional monomer, and having a gel content of from about 50 to 70 percent by weight of the polymer prior to sterilization.
A bandage construction comprising:
- (a) a sterilized backing;
- (b) a sterilized inherently tacky, pressure-sensitive adhesive layer on one side of said backing, said adhesive formed by emulsion polymerization and comprising on a polymerized basis and based on the total weight of the monomers:
- (i) about 48 percent by weight of an alkyl acrylate selected from the group consisting of 2-ethyl hexylacrylate and isooctyl acrylate;
- (ii) about 29 percent by weight of a diester of a dicarboxylic acid selected from the group consisting of di-2-ethylhexyl maleate and di-2-ethylhexyl fumarate and;
- (iv) about 1 percent by weight acrylic acid;
- (v) about 1 percent by weight methacrylic acid, said polymer being formed in the presence of a reactive surfactant and a gel content of at least 50 percent by weight.
- (c) a gauze adhered to a portion of the pressure-sensitive adhesive layer;
- (d) a release liner extending over said adhesive liner and gauze.
Dependencies are inferred from the claim text.