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US 5,182,067 AGranted
Process of making fibers of sulfonated poly(p-phenylene terephthalamide)
AssigneeE. I. Du Pont de Nemours and Company
InventorMinshon J. Chiou
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Abstract
Fiber made from PPD-T with 0.5 to 3.0% sulfur as bound sulfonic acid or sulfonate groups, is disclosed. The fiber has inherent viscosity greater than 4.5, yarn tenacity greater than 20 grams per denier, heat-aged strength retention of greater than 90%, and dipped cord strength greater than 18 gram per denier. The process for making the fiber includes PPD-T sulfonation by exposure to high concentration sulfuric acid in dope preparation under carefully controlled temperature and time.
Claims1
A process for making a fiber from sulfonated PPD-T comprising the steps of:
- (a) agitating substantially unsulfonated PPD-T having an intent viscosity greater than 6 in sulfuric acid having a concentration of 100.5 to 102.5% in an amount such that there is 17 to 20 weight percent of PPD-T in the sulfuric acid, for a duration of 1 to 3 hours at a temperature of 70.degree. to 80.degree. C. to dissolve and sulfonate the PPD-T;
- (b) extruding the resulting solution from an orifice through a layer of inert non-coagulating fluid into a coagulating bath to coagulate the resulting fiber;
- (c) washing the coagulated fiber in an aqueous fiber-washing solution;
- (d) drying the fiber to yield a dry as-spun fiber of PPD-T having an inherent viscosity greater than 4.5 and a sulfonation of 0.5 to 3.0% sulfur, as bound sulfonic acid or sulfonate groups.
1 more element
Dependencies are inferred from the claim text.