Process for treating ammonia and nitrite containing waters to reduce nitrogen oxide emissions therefrom
AssigneeUnion Oil Company of California
InventorsDarrell L. Gallup, John L. Featherstone
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AssigneeUnion Oil Company of California
InventorsDarrell L. Gallup, John L. Featherstone
Estimating the term…
A process is provided for controlling the emission of nitrogen dioxide from, and the growth of living organisms in, steam condensate cooling towers and catch basins used in conjunction with a condensate of steam derived from an ammonia containing geothermal brine. The process comprises contacting the condensate, in a substantially continuous manner, with a less-than-stoichiometric amount of an oxidizing agent, which results in the oxidation of nitrite in the condensate to a nitrate. The process optionally provides for periodically introducing a biocide into the condensate in an amount which controls organism growth in the cooling tower and catch basin. To prevent system corrosion, the process may include treating the condensate with a non-organic, phosphate-based corrosion inhibitor and scale dispersant.
A process for treating an aqueous solution containing nitrite to prevent emission of nitrogen dioxide therefore comprising contacting the aqueous solution with an oxidizing agent in an amount substantially less than that which theoretically would be required to react stoichiometrically with substantially all the nitrite in the aqueous solution, wherein said oxidizing agent includes at least one of the groups consisting of ##STR8## wherein X is a halogen.
A process for treating a condensate of steam derived from an aqueous brine containing nitrite, said method comprising contacting said condensate with a halogenated, organic, oxidizing agent in an amount less than the stoichiometric amount required to oxidize all the nitrite in the condensate to nitrate, instead wherein the oxidizing agent includes at least one ##STR13## wherein X is a halogen.
A process for use in a system for handling a flow of condensate of steam, the condensate containing ammonia and/or ammonia precursors, the process controlling the emission of nitrogen dioxide from, and a concentration of one or more organisms selected from the group consisting of fungi, algae and bacteria growing in, the condensate handling system, the process comprising the steps of:
A process for use in a system in which a flow of ammonia-containing steam derived from a geothermal fluid is used to generate electric power, and which includes:
A process comprising reducing the emission of one or more oxides of nitrogen from a system handling aqueous liquids containing oxidizable nitrogen components by adding to at least one of said liquids an oxidizing agent which comprises a heterocyclic ring compound having from 5 to 6 atoms in at least one ring in an amount stoichiometrically insufficient to oxidize all the oxidizable nitrogen components in said at least one liquid to nitrates.
A process for treating a condensate of steam, derived from an aqueous brine containing nitrite, and a concentration of one or more organisms selected from the group consisting of algae, fungi and bacteria by introducing into said condensate a halogenated, organic, oxidizing biocide in an amount sufficient to result in oxidation of substantially all the nitrite in the condensate, but insufficient to substantially inhibit an increase in the concentration of said organism in said condensate.
A process comprising substantially eliminating the emission of one or more oxides of nitrogen from a system handling aqueous geothermal liquid having liquid streams containing oxidizable nitrogen components by adding an oxidizing agent to at least one of said streams in an amount stoichiometrically insufficient to oxidize all the oxidizable nitrogen components theoretically in the at least one stream to nitrates.
Dependencies are inferred from the claim text.