Back to results
US 5,180,830 AGranted
Process for preparing hindered amine light stabilizers
AssigneeHimont Incorporated
InventorsGleason O. Cookson, Vu A. Dang, Krishna Raman
Life of this patent
Estimating the term…
Abstract
Disclosed is a process for the preparation of hindered amine light stabilizers by reacting (a) an alkyl substituted-4-hydroxypiperidine with (b) a dicarboxylic acid ester, in the presence of a catalyst system comprising a basic inorganic compound and a polar aprotic organic compound.
Claims17
A process for preparing hindered amine light stabilizers by reacting (a) an alkyl substituted-4-hydroxypiperidine having the following general formula:
- ##STR3## where R' is hydrogen or methyl, with (b) a dicarboxylic acid ester of the formula:
- ##STR4## where R" and R"' are a C.sub.1 -C.sub.12 linear or branched alkyl, a C.sub.5 -C.sub.12 cycloalkyl, a C.sub.6 -C.sub.12 aryl or a C.sub.7 -C.sub.12 alkaryl or aralkyl and may be the same or different, and n is a number from 1-12, in the presence of a polar aprotic organic compound and basic inorganic compound catalyst system, wherein a 2:1 to 3.2:1 mole ratio of alkyl substituted-4-hydroxypiperidine to dicarboxylic acid ester is used, and said polar aprotic compound has sufficient polarity to dissolve the ingredients at the reaction temperature and is capable of complexation with the metal ion of said basic inorganic compound.
Dependencies are inferred from the claim text.