Derivatization of arylene sulfide polymers
AssigneePhillips Petroleum Company
InventorDirk M. Sutherlin
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Abstract
An arylene sulfide polymer having derivatized end-groups and a process for preparing derivatized arylene sulfide polymer comprising contacting at an elevated temperature, an arylene sulfide polymer, a compound having the formula ##STR1## wherein R' is selected from the group consisting of an alkyl radical having 1 to about 17 carbon atoms, an aryl radical having 6 to about 16 carbon atoms, and combinations thereof and X is selected from the group consisting of chlorine and bromine, and a solvent which is stable in the presence of the compound and is capable of dissolving the arylene sulfide polymer.
Claims13
A derivatized arylene sulfide polymer composition having end-groups comprising the structure ##STR16## wherein Y is selected from the group consisting of --O--, --NH--, --S--, and --NR"'--, R"' is selected from the group cosisting of an alkyl radical of 1 to about 4 carbon atoms, a cycloalkyl radical of 3 to about 8 carbon atoms and combinations thereof, R' is selected from the group consisting of an alkyl radical having 1 to about 17 carbon atoms, an aryl radical having 6 to about 16 carbon atoms and combinations thereof, and Ar is selected from the group consisting of ##STR17## and combinations thereof wherein Ar' is a divalent radical selected from the group consisting of ##STR18## Z is selected from the group consisting of --SO.sub.2 -- and --CO--, m is 0 or 1, n is 0 or 1, A is selected from the group consisting of oxygen, sulfur, sulfonyl, and CR.sub.2, wherein each R is selected from the group consisting of hydrogen and alkyl radicals having 1 to about 4 carbon atoms, the total number of carbon atoms in all of the R groups in the molecule being 1 to about 12, wherein said arylene sulfide polymer is represented by a formula selected from the group consisting of ##STR19## and copolymers thereof.
A derivatized arylene sulfide polymer composition having end-groups comprising the structure ##STR22## wherein Y is selected from the group consisting of --O--, --NH--, --S--, and --NR"'--;
- R"' is selected from the group consisting of an alkyl radical of 1 to about 4 carbon atoms, a cycloalkyl radical of 3 to about 8 carbon atoms and combinations thereof, R' is selected from the group consisting of an alkyl radical having 1 to about 17 carbon atoms, an aryl radical having 6 to about 16 carbon atoms and combinations thereof, and Ar is selected from the group consisting of ##STR23## and combinations thereof wherein Ar' is a divalent radical selected from the group consisting of ##STR24## Z is selected from the group consisting of --SO.sub.2 -- and --CO--, m is 0 or 1, n is 0 or 1, A is selected from the group consisting of oxygen, sulfur, sulfonyl, and CR.sub.2, wherein each R is selected from the group consisting of hydrogen and alkyl radicals having 1 to about 4 carbon atoms, the total number of carbon atoms in all of the R groups in the molecule being 0 to about 12;
- wherein said derivatized arylene sulfide polymer composition is produced by a process comprising contacting:
- (a) an arylene sulfide polymer characterized by the repeating unit --AR--S-- wherein Ar is as defined above,
- (b) a compound having the formula ##STR25## wherein R' is defined above and X is selected from the group consisting of chlorine and bromine, and
- (c) a solvent wherein said solvent is stable in the presence of said compound and said arylene sulfide polymer is soluble in said solvent, wherein said contacting is performed at an elevated temperature.
Dependencies are inferred from the claim text.