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US 5,180,572 AGranted
Conversion of hydrogen sulfide to sulfur and hydrogen
AssigneeMarathon Oil Company
InventorMark A. Plummer
Life of this patent
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Abstract
The invention relates to a process for converting hydrogen sulfide to sulfur and hydrogen. The hydrogen sulfide gas is contacted with a quinone in an aqueous solvent containing a sulfur complexing agent to yield sulfur and the corresponding hydroquinone. The hydroquinone is converted back to quinone and hydrogen. The quinone is recycled and the hydrogen gas and sulfur is collected. The invention also discloses a range of ratios of complexing agent to quinone which produces an unexpected yield for the disclosed reaction.
Claims17
A process for converting hydrogen sulfide gas to sulfur and hydrogen gas comprising the steps of:
- a) contacting said hydrogen sulfide gas with a water-soluble quinone which is dissolved in an aqueous solvent containing a complexing agent, said aqueous solvent consisting essentially of water, said complexing agent selected from the group consisting of amines, amides, ureas, and mixtures thereof being present in said aqueous solvent in a range of about 1 mole of said complexing agent to about 4 moles of said quinone to about 1 mole of said complexing agent to about 32 moles of said quinone and reacting with said hydrogen sulfide to form a quaternary ion complex:
- b) reacting said hydrogen sulfide gas with said quinone to produce sulfur and a hydroquinone dissolved in said aqueous solvent containing said complexing agent;
- c) separating said sulfur from said aqueous solvent and said complexing agent;
- d) dehydrogenating said hydroquinone dissolved in said aqueous solvent containing said complexing agent to produce hydrogen gas and to regenerate said quinone dissolved in said aqueous solvent and said complexing agent;
- and
- e) recycling said quinone in said aqueous solvent and complexing agent to step a).
3 more elements
Dependencies are inferred from the claim text.