Antioxidant additive and lubricating oil containing same
AssigneeEthyl Petroleum Additives, Inc.
InventorsEdward F. Zaweski, Scott A. Culley
Life of this patent
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Abstract
An additive for improving the antioxidation properties of lubricating oil is made by reacting a sulfur halide selected from sulfur monochloride or sulfur dichloride with an aliphatic monoolefin (e.g. isobutene) to form an adduct, reacting the adduct thus formed with an alkali metal salt of an organocarbamodithioic acid in an aqueous alkanol medium and recovering the reaction product. When added to lubricating oil, the additive products of the invention improve the antioxidation properties of the lubricating oil.
Claims3
A lubricating oil composition comprising a major proportion of a mineral or synthetic lubricating oil and a minor proportion sufficient to improve its antioxidant properties of at least one lubricating oil additive made by the process of (i) reacting at a temperature of from about 30.degree.-100.degree. C. a sulfur halide selected from sulfur monochloride or sulfur dichloride with an aliphatic monolefin in an amount of about 0.4-1.5 gram moles of monolefin for each 0.3-0.75 gram mole of sulfur halide to produce an adduct, (ii) reacting said adduct in an aqueous alkanol medium at a temperature of about 50.degree. C. up to reflux with an alkali metal salt of an organocarbamodithioic acid having the formula:
- ##STR5## wherein R is an organic radical selected from an alkyl group, an alkenyl group, an aryl group or an aralkyl group in which the alkyl and alkenyl groups contain up to 32 carbon atoms and the aryl and aralkyl groups contain up to 15 carbon atoms and R' is hydrogen or an organic radical selected from an alkyl group, an alkenyl group, an aryl group or an aralkyl group in which the alkyl and alkenyl groups contain up to 32 carbon atoms and the aryl and aralkyl groups contain up to 15 carbon atoms in an amount of from about 0.1 to 0.6 mole of adduct for each mole of alkali metal salt of organocarbamodithioic acid, and (iii) recovering said additive.
An additive concentrate adapted for addition to lubricating oil to provide a formulated lubricating oil suitable for use in the crankcase of an internal combustion engine, said concentrate containing a diluent oil and an amount sufficient to improve the antioxidant property of said lubricating oil of at least one oil additive made by the process of (i) reacting at a temperature of from about 30.degree.-100.degree. C. a sulfur halide selected from sulfur monochloride or sulfur dichloride with an aliphatic monolefin in an amount of about 0.4-1.5 gram moles of monolefin for each 0.3-0.75 gram mole of sulfur halide to produce an adduct, (ii) reacting said adduct in an aqueous alkanol medium at a temperature of about 50.degree. C. up to reflux with an alkali metal salt of an organocarbamodithioic acid having the formula:
- ##STR6## wherein R is an organic radical selected from an alkyl group, an alkenyl group, an aryl group or an aralkyl group in which the alkyl and alkenyl groups contain up to 32 carbon atoms and the aryl and aralkyl groups contain up to 15 carbon atoms and R' is hydrogen or an organic radical selected from an alkyl group, an alkenyl group, an aryl group or an aralkyl group in which the alkyl and alkenyl groups contain up to 32 carbon atoms and the aryl and aralkyl groups contain up to 15 carbon atoms in an amount of from about 0.1 to 0.6 mole of adduct for each mole of alkali metal salt of organocarbamodithioic acid, and (iii) recovering said additive.
Dependencies are inferred from the claim text.