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US 5,177,282 AGranted
Oligomerization of olefins
AssigneeHuels Aktiengesellschaft
InventorsFranz Nierlich, Joachim Neumeister, Thomas Wildt, Wilhelm Droste, Fritz Obenaus
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Abstract
Olefins are oligomerized by passing a hydrocarbon feedstock mixture containing olefins of from 2 to 8 carbon atoms over a molecular sieve having a pore diameter of from greater than 4 angstroms to 15 angstroms, and then oligomerizing said olefins by passing the hydrocarbon feedstock over a nickel-containing catalyst at a temperature of from 0.degree.to 200.degree. C. and at a pressure of from 1 to 70 bar absolute.
Claims12
A process for oligomerizing olefins, comprising:
- passing a hydrocarbon feedstock mixture containing olefins of from 2 to 8 carbon atoms over a molecular sieve having a pore diameter of from greater than 4 angstroms to 15 angstroms, thereby removing catalyst poisons from the feedstock mixture;
- removing polyunsaturated hydrocarbons from the hydrocarbon feedstock mixture by selective hydrogenation either before or after passage of the hydrocarbon feedstock mixture over the molecular sieve;
- and then
- oligomerizing said olefins by passing the hydrocarbon feedstock over a nickel-containing catalyst at a temperature of from 0.degree. to 200.degree. C. and at a pressure of from 1 to 70 bar absolute.
1 more element
Dependencies are inferred from the claim text.