Water-dilutable, crosslinkable binder resin
AssigneeAkzo N.V.
InventorsGerardus J. W. M. Maters, Tamme Bartels
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Abstract
The present invention pertains to a crosslinkable binder resin comprising an acrylate copolymer backbone having as pendant groups water soluble half esters of dicarboxylic acid and crosslinkable olefinic groups which contain an activated ethylenic unsaturation, such as (meth)acryloyl groups. The (meth)acryloyl groups can be crosslinked by polyfunctional crosslinking agents such as amino or blocked amino crosslinkers. The water-soluble half esters preferably are formed by the reaction of pendant hydroxy groups with unsaturated cyclic anhydrides (the unsaturation providing an additional crosslinking site). The (meth)acryloyl groups preferably are formed by the reaction of pendant epoxy groups with (meth)acrylic acid or derivatives thereof.
Claims7
A method of producing a water-dilutable, crosslinkable acrylate copolymer binder resin, wherein the method comprises the steps of:
- (a) reacting the following compounds to form a copolymer:
- (1) 5-70% by weight of one or more epoxy group-containing (meth)acrylate compounds;
- (2) 3-30% by weight of one or more hydroxy-functional (meth)acrylate compounds;
- and
- (3) 0-92% by weight of one or more monomers copolymerizable with (1) or (2);
- (b) subsequent to step (a) converting at least a portion of the pendant epoxy groups to (meth)acryloyl groups using (meth)acrylic acid or an epoxy group-reactive derivative thereof:
- and
- (c) subsequent to step (a), converting at least a portion of the pendant hydroxy groups originating from the hydroxy-functional (meth)acrylate compounds to half esters by reaction with a cyclic dicarboxylic anhydride.
An aqueous coating composition comprising a water-dilutable, crosslinkable acrylic copolymer binder resin having pendant therefrom
- (i) groups comprising water-soluble half esters of a dicarboxylic acid and
- (ii) olefinic groups which can be crosslinked, said copolymer binder comprising the reaction product of:
- (a) a (meth)acrylate copolymer possessing pendant epoxy and hydroxyl groups, prepared from
- (1) 5-70% by weight of one or more epoxy group-containing compounds or monomers,
- (2) 3-30% by weight of one or more hydroxyl functional (meth)acrylate compounds or monomers and
- (3) 0-92% by weight of one or more other addition polymerizable monomers copolymerizable with (1) and (2);
- with
- (b) (meth)acrylic acid or an epoxy group-reactive derivative thereof, thereby resulting in activated unsaturated groups pendant from the (meth)acrylate copolymer;
- and then
- (c) a cyclic dicarboxylic anhydride, thereby resulting in acid groups pendant from the (meth)acrylate copolymer, at least a portion of said pendant acid groups having been neutralized to render the (meth)acrylate copolymer water-dilutable.
Dependencies are inferred from the claim text.