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US 5,177,042 AGranted
High activity vanadium-based catalyst
AssigneeUnion Carbide Chemicals & Plastics Technology Corporation
InventorsKevin J. Cann, James W. Nicoletti
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Abstract
A vanadium-based catalyst system is treated with an ether as a means of enhancing catalyst activity and polymer productivity.
Claims20
A catalyst system comprising:
- (A) a solid catalyst component consisting essentially of
- (1) a solid, particulate, porous inorganic carrier, as support for
- (2) the reaction product of (a) of vanadium trihalide and (b) an electron donor, and
- (3) a boron halide or alkyl-aluminum modifier,
- (B) a triethylaluminum cocatalyst,
- (C) a halohydrocarbon polymerization promoter, and
- (D) an ether activity enhancer having the formula:
- R.sup.1 --O--R.sup.2
- wherein:
- R.sup.1 and R.sup.2 are independently monovalent hydrocarbon radicals free of aliphatic unsaturation containing from 1 to 20 carbon atoms, or together make up an aliphatic ring containing from 2 to 20 carbon atoms,
- said ether activity enhancer being present in an amount sufficient to provide a molar ratio of such ether to the triethylaluminum cocatalyst of from 0.2:1 to 0.8:1.
8 more elements
In a catalyst system comprising:
- (A) a solid catalyst component consisting essentially of
- (1) a solid, particulate, porous inorganic carrier, as support for
- (2) the reaction product of (a) a vanadium trihalide and (b) an electron donor, and
- (3) a boron halide or alkyl-aluminum modifier,
- (B) a triethylaluminum cocatalyst, and
- (C) a halohydrocarbon polymerization promoter,
- the improvement wherein an ether activity enhancer is present in the catalyst system, said ether having the formula:
- R.sup.1 --O--R.sup.2
- wherein:
- R.sup.1 and R.sup.2 are independently monovalent hydrocarbon radicals free of aliphatic unsaturation containing from 1 to 20 carbon atoms, or together make up an aliphatic ring containing from 2 to 20 carbon atoms,
- said ether activity enhancer being present in an amount sufficient to provide a molar ratio of such either to the triethylaluminum cocatalyst of from 0.2:1 to 0.8:1.
8 more elements
Dependencies are inferred from the claim text.