Electrode for secondary battery
AssigneeMitsubishi Petrochemical Co., Ltd.
InventorsMitsutaka Miyabayashi, Manabu Hayashi, Eiki Yasukawa, Kikuko Miyata, Mitsumasa Kaitoh, Hiroshi Yui
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Abstract
Disclosed is an electrode for secondary battery, which comprises lithium or an alkali metal composed mainly of lithium doped as the active substance in a carrier composed of a mixture of a carbonaceous material satisfying the following conditions (A) and an organic polymer having ion conductivity of lithium. (A) a carbonaceous material with a hydrogen/carbon (H/C) atomic ratio of less than 0.15, a spacing (d.sub.002) of the (002) plane according to the X-ray wide angle diffraction method of 3.37 to 3.75 .ANG. and a crystallite size in the c-axis direction (Lc) of 5 .ANG. or more.
Claims12
An electrode for a secondary battery, comprising:
- a carrier doped with lithium or lithium containing another alkali metal as the active substance, said carrier composed of a mixture of (i) from 30 to 98% by weight of a carbonaceous material having a hydrogen/carbon (H/C) atomic ratio of less than 0.15, a spacing (d.sub.002) of the (002) plane as determined by X-ray wide angle diffraction of 3.37 to 3.75 .ANG., a total fine pore volume of 1.5.times.10.sup.-3 ml/g or more and a crystallite size in the c-axis direction (Lc) of 5 .ANG. or more, and (ii) from 2 to 70% by weight of a conductive polymer composition composed of lithium ion or lithium containing another alkali metal and an ion conducting polymer selected from the group consisting of
- (A) a polymer gel electrolytic composition comprising (a) a vinyl series polymer, as a matrix polymer which is obtained by polymerizing a monomer selected from the group consisting of alkyl(meth)acrylates, (meth)acrylonitrile, vinyl acetate, N-vinyl lactams, (meth)acrylic acid, hydroxyalkyl(meth)acrylates, (meth)acrylamide, glycerin mono(meth)acrylate, polyalkylene glycol(meth)acrylates, alkoxypolyalkylene glycol mono(meth)acrylates and siloxane-modified polyalkylene glycol(meth)acrylates, (b) an orangic solvent, and (c) 1,3,2,4-dibenzylidene sorbitol derivatives having at least one -COOR group, wherein R represents a hydrocarbon group having 1 to 20 carbon atoms, and
- (B) a polymer composition comprising polyphosphazene represented by the formula:
- ##STR5## wherein R.sup.1 and R.sup.2 each represent an alkyl group having 1 to 6 carbon atoms, n is an integer of 5 or more and m is an integer of 1 to 100, said polymer composition having an ion conductivity at 20.degree. C. or 10.sup.-8 S/cm or greater.
Dependencies are inferred from the claim text.