Cyclic preparation of cyclohexene oxide, cyclohexanol and cyclohexanone

A cyclic process for the preparation of cyclohexene oxide, cyclohexanol and cyclohexanone which includes the following steps:

• a) preparation of a mixture essentially comprising cyclohexyl hydroperoxide, cyclohexanol, cyclohexanone and cyclohexane by oxidizing cyclohexane using molecular oxygen or a gas containing molecular oxygen at from 130.degree. to 200.degree. C. and at from 5 to 125 bar in the liquid phase,
• b) joint distillative separation of the mixture from step a) and an epoxidation mixture produced in step c) and containing cyclohexene oxide, to give the following fractions
• b.sub.1) a fraction which essentially comprises cyclohexane and cyclohexene and is recycled into step a) after hydrogenation,
• b.sub.2) a fraction which essentially comprises cyclohexene oxide,
• b.sub.3) a mixture which essentially comprises cyclohexanol and cyclohexanone, and
• b.sub.4) a mixture which essentially comprises cyclohexyl hydroperoxide, cyclohexanol, cyclohexanone and catalyst,
• and
• c) reaction of the mixture obtained as fraction b.sub.4) and containing cyclohexyl hydroperoxide with cyclohexene in a mixture with cyclohexane at elevated temperature in the presence of transition-metal compounds from group 4 to 6 of the periodic table, to give an epoxidation mixture which essentially comprises cyclohexene oxide, cyclohexanol, cyclohexanone, cyclohexene, cyclohexane and catalyst and is separated by distillation in step b) together with the mixture from a).