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US 5,175,299 AGranted
Benzoic acid derivatives useful as intermediates for the preparation of herbicidal 4-benzoylpyrazoles
AssigneeNissan Chemical Industries, Ltd.
InventorsMasatoshi Baba, Takuya Kakuta, Norio Tanaka, Eiichi Oya, Takashi Ikai, Tsutomu Nawamaki, Shigeomi Watanabe
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Abstract
A pyrazole derivative having the formula ##STR1## is disclosed; the groups A, B, Q, V, W, X, Y, and Z are defined in the description.
Claims54
A benzoic acid of the formula
- wherein:
- X is an alkyl group having from 1 to 6 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms or a halogen atom;
- Z is Cl, --SR or --SO.sub.2 R wherein R is an alkyl group of 1 to 6 carbon atoms;
- and
- Y is --COOR;
- wherein R' is an alkyl group having from 1 to 6 carbon atoms, an alkyl group having from 1 to 6 carbon atoms substituted by an alkoxy or alkyl alkoxy which may be a halogenated group having from 1 to 6 carbon atoms, a haloalkyl group having from 1 to 6 carbon atoms or a cyclohexyl group,
- an alkyl group having from 1 to 6 carbon atoms substituted by thioalkyl wherein the alkyl group has from 1 to 6 carbon atoms;
- an alkyl group having from 1 to 6 carbon atoms substituted by hydroxy;
- an alkyl group having from 1 to 6 carbon atoms substituted by --CN;
- an alkyl group having from 1 to 6 carbon atoms substituted by acyloxy having from 1 to 6 carbon atoms;
- an alkyl group having from 1 to 6 carbon atoms substituted by a piperidine group;
- an alkyl group having from 1 to 6 carbon atoms substituted by an alkynyloxy group having from 1 to 6 carbon atoms;
- an alkyl group having from 1 to 6 carbon atoms substituted by an alkenyloxy group having from 1 to 6 carbon atoms;
- an alkenyl radical having from 1 to 6 carbon atoms substituted by an alkoxy group having from 1 to 6 carbon atoms;
- or a dialkyl amide radical wherein the alkyl radicals have from 1 to 6 carbon atoms.
12 more elements
A benzoic acid of the formula ##STR38## wherein:
- X is --CH.sub.3, Cl or --OCH.sub.3,
- Z is Cl, --SCH.sub.3 or --SO.sub.2 CH.sub.3, and
- Y is --CH.sub.2 OCH.sub.3, --COOCH.sub.3, --CH.sub.2 OC.sub.2 H.sub.5, --CH(CH.sub.3)OCH.sub.3, --COOi--Pr, --CH.sub.2 Oi--Pr, --COOCH.sub.2 CH.sub.2 OCH.sub.3, --CH.sub.2 SC.sub.2 H.sub.5, --COOC.sub.2 H.sub.5, --CH.sub.2 OCH.sub.2 CH.sub.2 OCH.sub.3, ##STR39## --COO--cyclohexyl, --COOnPr, --CH.sub.2 OH, --CH(C.sub.2 H.sub.5)OCH.sub.3, --CH(CH.sub.3)OC.sub.2 H.sub.5, --CH.sub.2 OCH.sub.2 C.tbd.CH, --CH.sub.2 OCH.sub.2 CH.dbd.CH.sub.2, --CH.sub.2 OnAm, --COOiAm, --CH.sub.2 OCH.sub.2 CF.sub.3, --COOCH.sub.2 CH.sub.2 Cl, --CH.sub.2 CN, --CH.sub.2 OOCH.sub.3, --CH.dbd.CHOCH.sub.3 or --CON(C.sub.2 H.sub.5).sub.2.
Dependencies are inferred from the claim text.