Method for thermal conversion of methane and reactor for carrying out the method
AssigneeInstitut Francais du Petrole
InventorsJacques Alagy, Paul Broutin, Christian Busson, Jerome Weill
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AssigneeInstitut Francais du Petrole
InventorsJacques Alagy, Paul Broutin, Christian Busson, Jerome Weill
Estimating the term…
Method and apparatus for thermal conversion of methane to hydrocarbons of higher molecular weight, comprising a reactor 1 of elongated shape, connected at a first end to means 5 for supplying gas mixture containing methane (process gas), and connected at the opposite end to discharge means 10, the reactor having a plurality of electric heating means 3 surrounded by sheaths 4 over a first part (towards the first end). The heating means, which are substantially parallel, are arranged in sheets which are substantially parallel and perpendicular to the axis of the reactor, so that spaces or passages for circulation of the process gas and/or effluent are defined between the sheaths and/or between the sheaths and the walls 22 separating two consecutive sheets. The heating means are adapted to heat the passages by successive independent cross sections substantially perpendicular to the axis of the reactor. In a second part 8 (towards the opposite end) adjoining the first part, the reactor further comprises means 9 for cooling the effluent, connected to the means for supplying cooling fluid. The reactor also has means for introducing a gas containing hydrogen into the space surrounding the heating means inside the sheaths 4, at an appropriate pressure. The reactor and particularly the sheaths 4 are designed so that hydrogen is diffused from inside the sheaths to outside them and can then be diluted in the process gas.
In a method of thermal conversion of methane to hydrocarbons of higher molecular weight in an elongated reaction zone, comprising a heating zone and a cooling zone following said heating zone, said method comprising circulating a charge comprising a gas mixture containing methane in the heating zone in a direction of flow substantially parallel to the axis of the elongated reaction zone, said heating zone comprising a plurality of electric heating means arranged in substantially parallel sheets which form a bundle of triangular, square or rectangular pitch in transverse elevation, said heating means being grouped in successive cross sections substantially normal to the direction of the reaction zone, the sections being independent of one another and supplied with electricity so as to establish at least two parts in the heating zone, the first part enabling the charge to be brought to a maximum temperature of above about 750.degree. C. to no more than about 1500.degree. C. and the second part, which follows the first, enabling the charge to be maintained at a temperature substantially equal to said maximum temperature, and cooling effluent from the heating zone by introducing a cooling fluid into the cooling zone and collecting said hydrocarbons of higher molecular weight at the end of the reaction zone, the improvement wherein the electric heating means are insulated from direct contact with the gas mixture containing methane by sheaths into which a gas containing hydrogen is fed, said sheaths having sufficient permeability and said gas fed into said sheaths being at a sufficient pressure, such that at least part of the hydrogen is diffused from the inside of said sheaths to at least selected locations on the outside of said sheaths.
Dependencies are inferred from the claim text.