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US 5,159,009 AGranted
Carbon blacks modified with organosilicon compounds, method of their production and their use in rubber mixtures
AssigneeDegussa AG
InventorsSiegfried Wolff, Udo Gorl
Life of this patent
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Abstract
Carbon black is reacted with at least one organosilicon compound of the General Formula [R.sup.1.sub.n (RO).sub.3-n Si-(Alk).sub.m -(Ar).sub.p ]q [B](I) R.sup.1.sub.n (RO).sub.3-n Si-(Alkyl) (II) or R.sup.1.sub.n (RO).sub.3-n Si-(Alkenyl) (III), and any excess of said organosilicon compound is extracted with a solvent. The products are useful as active fillers in rubber mixtures, carbon black suspensions and plastic mixtures which can be cross-linked with sulfur or peroxide.
Claims7
Carbon blacks which are chemically modified with at least one organosilicon compound selected from the group consisting of
- [R.sup.1.sub.n (RO).sub.3-n Si-(Alk).sub.m -(Ar).sub.p ]q [B](I)
- R.sup.1.sub.n (RO).sub.3-n Si-(Alkyl) (II)
- R.sup.1.sub.n (RO).sub.3-n Si-(Alkenyl) (III)
- in which
- B represents --SCN, --SH, --Cl, --NH.sub.2 (if q=1) or --Sx--(if q=2),
- R and R.sup.1, which may be the same or different, represent an alkyl group containing 1 to 4 carbon atoms or the phenyl group,
- q represents 1 or 2,
- n represents 0, 1 or 2,
- Alk represents a bivalent straight or branched hydrocarbon group containing 1 to 6 carbon atoms,
- m represents 0 or 1,
- Ar represents an arylene group containing 6 to 12 carbon atoms,
- p represents 0 or 1 provided that p and n do not simultaneously signify 0,
- x represents a number from 2 to 8,
- Alkyl represents a monovalent straight or branched unsaturated hydrocarbon group containing 1 to 20 carbon atoms,
- alkenyl represents a monovalent straight or branched unsaturated hydrocarbon group containing 2 to 20 carbon atoms,
- and on the surface of which blacks 0.1 to 15 % by weight of one or more of the named organosilicon compounds are bonded in such a manner that they can not be extracted with organic solvents.
13 more elements
Dependencies are inferred from the claim text.