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US 5,147,747 AGranted
Low fusing temperature tone powder of crosslinked crystalline and amorphous polyesters
AssigneeEastman Kodak Company
InventorsJohn C. Wilson, Lawrence P. DeMejo
Life of this patent
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Abstract
A low fusing temperature toner powder with good keep and broad fusing latitude characteristics is provided. The toner powder is comprised of polymer particles of a partially carboxylated crystalline polyester and partially carboxylated amorphous polyester that has been crosslinked together at elevated temperature with the aid of an epoxy novolac resin and a crosslinking catalyst.
Claims8
A process for preparing a polymer for a low fusing temperature toner powder comprising the steps of:
- (a) admixing;
- (1) about 25 to about 75 weight percent of a low molecular weight, crystalline polyester that has been esterified with pyromellitic dianhydride and has the formula:
- ##STR9## and has a glass transition temperature in the range of about -20.degree. to about 60.degree. C., a melting temperature in the range of about 60.degree. to about 120.degree. C., a number average molecular weight in the range of about 1,500 to about 5,000 and a weight average molecular weight in the range of about 3,000 to about 10,000, and containing about 2 carboxyl groups per molecule;
- (2) about 25 to about 75 weight percent of a low molecular weight, amorphous polyester that has been esterified with pyromellitic dianhydride and has the formula:
- ##STR10## and has a glass transition temperature in the range of about 50.degree. to about 90.degree. C., a number average molecular weight in the range of about 1,500 to about 5,000 and a weight average molecular weight in the range of about 3,000 to about 10,000, and containing about 2 carboxyl groups per molecule;
- (3) about 2 to about 10 weight percent of a low molecular weight epoxy novolac resin that has the formula:
- ##STR11## and has an epoxy functionality of about 4.8;
- and (4) about 0.5 to about 4 weight percent of a crosslinking catalyst;
- and
- (b) melt blending said mixture at a temperature in the range of about 90.degree. to about 180.degree. C.
7 more elements
Dependencies are inferred from the claim text.