Homogeneous rhenium catalysts for metathesis of olefins
AssigneeMassachusetts Institute of Technology
InventorsRichard R. Schrock, Robert Toreki
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Abstract
The invention pertains to rhenium (VII) compounds which are catalysts for metathesis of ordinary olefins (hydrocarbons) and functionalized olefins in a homogeneous phase and to methods of synthesizing these compounds. The rhenium compounds comprise a rhenium (VII) atom centrally linked to an alkylidene ligand, an alkylidyne ligand, and two other ligands of which at least one ligand is sufficiently electron withdrawing to render the rhenium atom significantly active for metathesis.
Claims17
A process for metathesizing an olefin, comprising the steps of:
- a. contacting an olefin in a solvent with a homogeneous metathesis catalyst under conditions sufficient for metathesis, the metathesis catalyst comprising a rhenium (VII) atom centrally linked to an alkylidene ligand, an alkylidyne ligand, and two other ligands of which at least one ligand is an electron withdrawing ligand in which its corresponding free ligand in protinated form has a pKa below about 9;
- wherein the catalyst has significant metathesis activity that can effect the metathesis of an ordinary, cyclic or functionalized olefin at room temperature at a rate of at least one turnover per hour, whereby the olefin is metathesized;
- and
- b. recovering one or more metathesis products.
A process for metathesizing an olefin, comprising the steps of:
- a) contacting an olefin in a solvent with a homogeneous rhenium catalyst under conditions sufficient for metathesis, the catalyst having the formula:
- ##STR5## wherein R.sup.1, R.sup.2 and R.sup.3 are individually selected from the group consisting of an alkyl having one to 20 carbon atoms, an aryl having six to 20 carbon atoms, an aralkyl having seven to 30 carbon atoms, halogen substituted derivative thereof and silicon-containing analogs thereof;
- and R.sup.2 further consists of a substituent resulting from the reaction of the Re.dbd.CHR.sup.2 moiety of the compound with an olefin that is being metathesized, whereby the olefin is metathesized;
- and
- b) recovering one or more metathesis products.
A process for metathesizing an olefin, comprising the steps of:
- a) contacting an olefin in a solvent with a homogeneous rhenium catalyst under conditions sufficient for metathesis, the catalyst having the formula:
- ##STR6## wherein R.sup.1 is selected from the group consisting of an alkyl having 1 to 20 carbon atoms, an aryl having 6 to b 20 carbon atoms, an aralkyl having 7 to 30 carbon atoms, halogen substituted derivative of each and silicon-containing analogs of each;
- R.sup.2 is selected from the group consisting of R.sup.1 or is a substituent resulting from the reaction of the Re=CHR.sup.2 moiety of the compound with an olefin that is being metathesized;
- R.sup.3 and R.sup.4 are individually selected from groups consisting of R.sup.1, a halogen, triflate, and concatenated combinations of R.sup.3 and R.sup.4 ;
- wherein R.sup.3 and R.sup.4 individually may contain alkoxide oxygen atoms which are bound to the rhenium atom;
- n is a positive integer, whereby the olefin is metathesized;
- and
- b) recovering one or more metathesis products.
Dependencies are inferred from the claim text.