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US 5,139,879 AGranted
Fluoropolymer blend anti-reflection coatings and coated articles
AssigneeAllied-Signal Inc.
InventorsShaul M. Aharoni, Ajay Nahata, James T. Yardley
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Abstract
Solid bodies having a reflective surface are provided with an anti-reflection coating of a fluoropolymer blends of (1) a terpolymer composition derived from (a) perfluoroalkylakyl acrylate or methacrylate, (b) acrylic, methacrylic or itaconic acid, and (c) hydroxyl- containing acrylate or methacrylate; and (2) an amorphous fluoropolymer.
Claims24
A solid body having a reflective surface, having deposited thereon as an anti-reflection coating a layer of a polymeric composition comprising a blend of
- (a) from about 1 to about 95 percent by weight of amorphous fluoropolymer, with
- (b) from about 5 to about 99 percent by weight of a fluorinated copolymer having a polymer chain composed of
- --X.sub.s --Y.sub.t --Z.sub.u --
- units, wherein
- s, t and u represent weight proportions of the respective X, Y and Z units, and have values within the ranges of
- s=from about 0.5 to about 0.995;
- t=from about 0.0025 to about 0.4975;
- and
- u=from about 0.0025 to about 0.4975;
- with the sum of s+t+u being 1;
- X represents units of the composition ##STR8## wherein R.sup.1 is H, --CH.sub.3, or mixtures thereof;
- p is 1 or 2;
- n is an integer of from about 1 to about 40;
- Y represents units of the composition ##STR9## wherein R.sup.2 is H, --CH.sub.3 or --CH.sub.2 COOH;
- Z represents units of the composition ##STR10## wherein R.sup.3 is H, --CH.sub.3, or CH.sub.2 COOC.sub.m H.sub.2m+1, wherein m is an integer of from about 1 to about 4, and
- R.sup.4 is an alkylene bridging group, straight chain, branched or cyclic, having from 1 to about 8 carbon atoms;
- wherein the X, Y and Z units may be arranged in any sequence, said amorphous fluoropolymer retainting its amorphicity in said blend and not phase separating during or after any curing.
14 more elements
Dependencies are inferred from the claim text.