Production method of goethite
AssigneeMitsui Toatsu Chemicals, Inc.
InventorsMitsurou Matsunaga, Isamu Morita, Nobuhiro Fukuda
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Abstract
A method for producing goethite having an axial ratio of at least 7 and a specific surface area of 20-80 m.sup.2 /g and suitable for use in the production of .alpha.-iron powder, which method comprises intermittently feeding an oxidizing gas into a suspension of ferrous hydroxide, which has been obtained by reacting a ferrous salt with an alkali hydroxide, preferably while controlling the oxidation rate of ferrous hydroxide below 7% per each feeding-feed-stopping cycle of the oxidizing gas and also controlling the feeding time period of the oxidizing gas within 10 minutes and shorter than a quarter of the feed-stopping time period per each feeding-feed-stopping cycle of the oxidizing gas.
Claims8
A method for producing goethite particles by oxidizing a ferrous hydroxide suspension, which has been obtained by reacting a ferrous salt solution with an alkali hydroxide solution, with an oxidizing gas, which method comprises intermittently feeding the oxidizing gas into the suspension, the oxidation percentage of ferrous hydroxide being 10 percent or less per time period of feeding and feed-stopping of the oxidizing gas, the feeding time period of the oxidizing gas being 10 minutes or shorter and shorter than a quarter of the feed-stopping time period of the oxidizing gas, the number of cycles of feeding and feed-stopping of the oxidizing gas being at least 10 times, and the oxidation being carried out by feeding and feed-stopping oxidizing gas at a temperature ranging to 20.degree. to 80.degree. C., until essentially all the ferrous hydroxide has been oxidized to goethite said method being conduced in a single stirred-type reactor, said geothite particles having a particle specific surface area of from 20 to 80 m.sup.2 /g, an axial ratio of least 7 and a coefficient of variation of 47.7 percent or less.
The method as claimed in claim the goethite wherein particles contain a non-ferrous metal selected from the group consisting of nickel, zinc, manganese, copper and chromium and are produced by oxidizing a ferrous hydroxide which has been obtained by coprecipitating iron together with said non-ferrous metal.
Dependencies are inferred from the claim text.