A catalyst in powdered form comprising a major amount of the oxides of a first metal selected from the group of copper or zinc and a second metal selected from chromium, molybdenum, tungsten and vanadium, and, optionally, a minor amount of the oxide of a promoter metal selected from the group consisting of manganese, barium, zinc, nickel, cobalt, cadmium, iron and any combination thereof, provided that promoter metal is not zinc if the first metal is zinc, and wherein the average particle diameter of the powder is from about 6 to about 20 microns;
- the particle surface area is from about 20 to about 70 m.sup.2 /g;
- the pore volume of pores having diameters in the range up to 120 .ANG. is from about 5 to about 45%, in the range of about 120 to about 350 .ANG. is from about 40 to about 80%, and in the range of about 350 to about 1000 .ANG. is from about 10 to about 40% of the total pore volume.