Sulfo group containing triphendioxazines having at least one 1,3,5-triazine ring
AssigneeSandoz Ltd.
InventorReinhard Pedrazzi
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Abstract
Sulpho group-containing dioxazine compounds corresponding to the formula ##STR1## in which the symbols are as defined in the specification, and salts thereof as well as dyeing preparations thereof are useful for dyeing or printing hydroxy group- or nitrogen-containing organic substrates, optionally combined with a special after-treatment of the dyed or printed textiles thus obtained to improve their wet fastness properties. Most preferred substrates are textile material containing or consisting of cellulose and paper.
Claims21
A compound of the formula ##STR65## or a salt thereof, wherein Q is a chromophoric radical of an azo, formazan, anthraquinone, phthalocyanine or dioxazine dye,
- each R is independently hydrogen, C.sub.1-6 -alkyl or C.sub.1-6 alkyl monosubstituted by halo, cyano, hydroxy, C.sub.1-4 -alkoxy, --COOH, --SO.sub.3 H or --OSO.sub.3 H,
- each of T.sub.1 and T.sub.2 is independently hydrogen;
- chloro;
- bromo;
- C.sub.1-4 alkyl;
- C.sub.1-4 alkoxy;
- C.sub.1-4 alkyl or C.sub.1-4 -alkoxy monosubstituted by chloro, methoxy, ethoxy or --OSO.sub.3 H;
- phenyl;
- phenoxy;
- or phenyl or phenoxy substituted by one or two substituents selected from chloro, bromo, methyl, ethyl, methoxy and ethoxy,
- each X is independently halo or --NR.sub.4 R.sub.5,
- wherein each of R.sub.4 and R.sub.5 is independently hydrogen;
- C.sub.1-6 alkyl;
- C.sub.1-6 alkyl monosubstituted by hydroxy, halo, cyano, C.sub.1-4 alkoxy, C.sub.1-4 hydroxyalkoxy, --COOH, --SO.sub.3 H or --OSO.sub.3 H;
- cyclohexyl;
- phenyl;
- phenyl substituted by one to three substituents selected from chloro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, --COOH, --SO.sub.3 H and --NH.sub.2 ;
- phenyl(C.sub.1-4 -alkyl) or phenyl(C.sub.1-4 alkyl) the phenyl ring of which is substituted by one to three substituents selected from chloro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, --COOH, --SO.sub.3 H and --NH.sub.2, or
- --NR.sub.4 R.sub.5 is pyrrolidino, piperidino, morpholino, piperazino or N'-R.sub.9 -piperazino,
- wherein R.sub.9 is methyl, ethyl, 2-hydroxyethyl or 2-aminoethyl,
- each Y.sub.1 is independently linear or branched C.sub.2-6 alkylene;
- linear or branched C.sub.3-6 alkylene monosubstituted or disubstituted by hydroxy;
- linear or branched C.sub.3-6 alkylene interrupted by --O--, --S-- or --NR--;
- cyclohexylene or cyclohexylene substituted by one to three methyl groups;
- ##STR66## wherein W is linear or branched C.sub.1-4 alkylene,
- the * denotes the carbon atoms attached to the nitrogen atom attached to Ring A or Ring B, and
- R is as defined above,
- each --NR--Y.sub.1 --NR-- is independently ##STR67## ##STR68## wherein R is as defined above,
- Y.sub.2 is linear or branched C.sub.2-6 alkylene;
- linear or branched C.sub.2-6 alkylene interrupted by --O--, --S-- or --NR--;
- linear or branched C.sub.3-6 alkylene monosubstituted or disubstituted by hydroxy;
- cyclohexylene;
- cyclohexylene substituted by one to three methyl groups;
- ##STR69## wherein A.sub.1 is linear or branched C.sub.1-4 alkylene,
- R.sub.3 is hydrogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, chloro, --COOH or --SO.sub.3 H, and R is as defined above, or ##STR70## wherein R is as defined above, each of m and n is independently 0 or 1, and
- each p is independently 0, 1 or 2,
- wherein
- each R.sub.1 is independently hydrogen, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy or --COOH,
- each W.sub.1 is independently linear or branched C.sub.2-4 alkylene,
- each q is independently 0 or 1, and
- each t is independently 0 or 1,
- wherein each halo is independently fluoro, chloro or bromo, with the proviso that the compound contains at least one sulfo group,
- or a mixture thereof.
Dependencies are inferred from the claim text.