Disperse dyes which are convertible into a thermomigration fast form
AssigneeCiba-Geigy Corporation
InventorsPeter Liechti, Martin Trottmann
Life of this patent
Estimating the term…
Loading patent…
AssigneeCiba-Geigy Corporation
InventorsPeter Liechti, Martin Trottmann
Estimating the term…
Disperse dyes, which produce dyeings of excellent thermomigration fastness, consisting of a chromophore and a lactam or oxime radical which detaches on heating to leave an isocyanate or isothiocyanate group, which reacts with a suitable group in the environment. The disclosed dyes are described by the formula ##STR1## where F is the radical of a dye which is free of water-solubilizing groups, B is a bridge member or a direct bond, Z is O or S and V is the radical of a group H--V, where H--V is an oxime of the formula ##STR2## or a lactam of the formula ##STR3## in which R.sup.1 and R.sup.2 are each independently of the other substituted or unsubstituted alkyl or aryl, or R.sup.1 and R.sup.2 together with the carbon atom linking them form a cycloaliphatic ring, R is hydrogen or alkyl and n is an integer from 4 to 11.
A disperse dye of the formula ##STR270## where F is the radical of a dye which is free of water-solubilizing groups, selected from the group consisting of nitro dyes, nitrodiphenylamine dyes, quinoline dyes, aminonaphthoquinone dyes, coumarin dyes, methine dyes, anthraquinone dyes, tricyanovinyl dyes and azo dyes,
A disperse dye of the formula ##STR275## where E is D--N.dbd.N-- or ##STR276## wherein D is the radical of a carbocyclic or heterocyclic diazo component selected from the group consisting of thienyl, phenylazothienyl, thiazolyl, isothiazolyl, 1,2,4-thiadiazolyl, 1,3,4-thiadiazolyl, benzothiazolyl, benzisothiazolyl, pyrazolyl, 1,2,3-triazolyl, 1,2,4-triazolyl and imidazolyl, or phenyl, each of these groups being unsubstituted or substituted by alkyl, alkoxy or alkylthio each of 1 to 4 carbon atoms, phenyl, halogen, trifluoromethyl, cyano, nitro, acetyl or benzoyl, carbo-C.sub.1 -C.sub.4 alkoxy, alkyl sulfone of 1 to 4 carbon atoms, phenyl sulfone, phenoxysulfonyl, sulfonamido or phenylazo, or where 2 adjacent substituents on the ring systems mentioned form further fused-on phenyl rings or cyclic imides,
A disperse dye of the formulae ##STR279## where D.sup.1 is a benzothiazolyl radical which is unsubstituted or monosubstituted or disubstituted by chlorine, or is a phenyl radical which is monosubstituted or disubstituted by nitro, chlorine, cyano, methylsulfonyl, ethylsulfonyl or phenylazo,
Dependencies are inferred from the claim text.